12107-04-9

Basic information

• Product Name: Iron, dicarbonylchloro(h5-2,4-cyclopentadien-1-yl)-
• Synonyms: Iron,chlorodicarbonylcyclopentadienyl- (6CI,7CI); Iron, dicarbonylchloro-p-cyclopentadienyl- (8CI); Chloro(cyclopentadienyl)irondicarbonyl; Chlorodicarbonyl(cyclopentadienyl)iron; Chlorodicarbonyl-p-cyclopentadienyl iron;Dicarbonyl(chloro)(h5-cyclopentadienyl)iron; Dicarbonylchloro(h-cyclopentadienyl)iron; Dicarbonylchloro-p-cyclopentadienyliron; Dicarbonylchlorocyclopentadienyliron;NSC 168789
• CAS NO: 12107-04-9
• Molecular Formula: C7H5 Cl Fe O2
• Molecular Weight: 212.415
• Mol File: 12107-04-9.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: Iron, dicarbonylchloro(h5-2,4-cyclopentadien-1-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Iron, dicarbonylchloro(h5-2,4-cyclopentadien-1-yl)-(12107-04-9)
• EPA Substance Registry System: Iron, dicarbonylchloro(h5-2,4-cyclopentadien-1-yl)-(12107-04-9)

Safety Data

• Hazardous Substances Data: 12107-04-9(Hazardous Substances Data)

Upstream product

• 12110-44-0 CpFe(CO)3SC6H5 
• 38117-54-3 cyclopentadienyl iron(II) dicarbonyl dimer 
• 672-66-2 Dimethyl(phenyl)phosphine 
• 1711-05-3 m-anisoyl chloride 
• 99-33-2 3,5-dinitrobenoyl chloride 
• 4397-55-1 phthalic monoacid monomethyl ester chloride 
• 101-02-0 triphenyl phosphite 
• 56-23-5 tetrachloromethane 
• 40834-71-7 2,3-dichloro-1,4,5,6,7,7-hexafluorobicyclo[2.2.1]hepta-2,5-diene 
• 38960-10-0 allyl(cyclopentadienyl)iron(II) dicarbonyl 
• 86392-66-7 (η5-C5H5)Fe(CO)2(CCl3) 
• 122-04-3 4-nitro-benzoyl chloride 
• 17084-13-8 potassium hexafluorophosphate 
• 17116-26-6 Ag(P(C₆H₅)3)3⁽¹⁺⁾*Cl^(1-) = Ag(P(C₆H₅)3)3Cl 

Downstream Products

• 38117-54-3 cyclopentadienyl iron(II) dicarbonyl dimer 
• 10108-64-2 cadmium(II) chloride 
• 102-54-5 ferrocene 
• 74-93-1 methylthiol 
• 624-92-0 Dimethyldisulphide 
• 6628-18-8 1,2-bis(methylthio)ethane 
• 3561-67-9 bis(phenylthio)methane 
• 622-20-8 1,2-bis(phenylthio)ethane 
• 882-33-7 diphenyldisulfane 
• 38117-54-3 di(cyclopentadienideiron dicarbonyl) 
• 15041-50-6 tetracobaltdodecacarbonyl 
• 58057-66-2 [Fe(SC₆H₄CH₃)(CO)2(C₅H₅)] 
• 1287-13-4 bis(η⁵-cyclopentadienyl)ruthenium 
• 12110-44-0 CpFe(CO)3SC6H5 

Relevant articles and documents

Organometallic sulfur complexes. III. Reactions of organoiron sulfanes, (μ-Sx)2 (x=3,4) and the synthesis of cyclopentadienyldicarbonyliron S-bonded monothiocarboxylates, FeCp(CO)2(SCOR)

The reaction of organoiron sulfanes, (μ-Sx)2 (x=3,4) with LiBEt3H at -97 deg C gives the anionic species - (x=1,2 or 3).The solution containing the anionic species reacts with acid chlorides RCOCl to give FeCp(CO)2(SCOR

Selenothiocarbonate complexes of iron: Structure of CpFe(CO) 2SeC(S)O-4-C6H4Cl

Stable complexes of general formula CpFe(CO)2SeC(S)OR, where R = Ph (1a), 4-C6H4Cl (1b), 4-C6H4F (1c), C6F5 (1d), 4-C6H4CH 3 (1e), were prepared by the reaction of (μ-Se)[CpFe(CO) 2]2 with ROC(S)Cl at room temperature. When a THF solution of 1 was photolyzed the chelate complexes CpFe(CO)(κ2Se,S- SeC(S)OR) (2) were obtained in good yields. All of these complexes have been characterized by elemental analyses, IR and 1H NMR spectroscopy. The structure of CpFe(CO)2SeC(S)O-4-C6H4Cl (1b) is reported.

Iron Se-bonded mono-selenocarbonates CpFe(CO)2SeCO2R: The first selenocarbonate complexes

The reactivity of the iron selenide complex (μ-Se)[CpFe(CO) 2]2 toward chloroformates, ROCOCl, has been studied and the products CpFe(CO)2SeCO2R [R=Me (1), Et (2), iso-Bu (3), Ph (4), 2-C6H4/sub

Preparation and organic transformation reactions of CpFe(CO)2SCO-3-C6H4-SO2Cl

Treatment of the iron sulfides (μ-Ss)[CpFe(CO)2]2 with 3-ClCOC6H4SO2Cl gave the novel organoiron thiocarboxylate complex CpFe(CO)2SCO3-C6H4SO2Cl which contains a free sulfonyl chloride group. This complex reacts with nucleophiles such as R2NH, ArOH and RSH to give stable complexes CpFe b = 9.2395(2), c = 13.4341(4) A?, βB = 95.403(2)°, V = 2219.26(10) A?3 and Z = 4.