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η6-dibenzyl chromium tricarbonyl is an organometallic compound with the chemical formula (C6H5CH2)2Cr(CO)3. It features a chromium atom bonded to two benzyl groups (C6H5CH2) in an η6 manner, meaning that the metal atom interacts with all six carbon atoms of the benzene rings. Additionally, the chromium is also coordinated to three carbon monoxide (CO) ligands. η6-dibenzyl chromium tricarbonyl is known for its unique structure and reactivity, often used as a precursor in the synthesis of various organometallic complexes and in catalytic applications. It is characterized by its stability and the ability to participate in various chemical reactions, making it an important compound in the field of organometallic chemistry.

32825-33-5

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32825-33-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 32825-33-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,2,8,2 and 5 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 32825-33:
(7*3)+(6*2)+(5*8)+(4*2)+(3*5)+(2*3)+(1*3)=105
105 % 10 = 5
So 32825-33-5 is a valid CAS Registry Number.

32825-33-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name η6-dibenzyl chromium tricarbonyl

1.2 Other means of identification

Product number -
Other names (bibenzyl)tricarbonylchromium

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:32825-33-5 SDS

32825-33-5Relevant academic research and scientific papers

Neighboring Group Participation in Organometallic Chemistry: Internal Exchange in (Diarylalkane)tricarbonylchromium Complexes

Traylor, Teddy G.,Goldberg, Martin J.

, p. 3968 - 3973 (2007/10/02)

The rates of internal and external exchange of (diarylalkane)tricarbonylchromium complexes in benzene/cyclohexane mixtures have been determined.Neighbouring group participation is demonstrated in all complexes and follows an order with respect to ring siz

Electrophilic Substitution in (Arene)tricarbonylchromium Complexes. Part 1.

von Rosenberg, Joseph L.,Pinder, A. Reginald

, p. 747 - 752 (2007/10/02)

The Friedel-Crafts acetylation of several (arene)tricarbonylchromium complexes have been investigated.From the results it is concluded that the tricarbonylchromium group deactivates to a small extent towards electrophilic substitution the ring to which it is attached.In the case of tricarbonyl(diphenylmethane)chromium (1; n=1), however, attack occurred on both rings to about an equal extent, possible explanations for this unexpected behaviour are advanced.

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