32841-83-1Relevant academic research and scientific papers
Asymmetrically Difunctionalized 1,1′-Ferrocenyl Metalloligands and Their Transition Metal Complexes
Anson, Christopher E.,Barani, Elham,Bayer, Lea,Breher, Frank,Fink, Karin,Frank, Nils,Powell, Annie K.,Wagner, Hanna E.
, (2022/01/20)
The synthesis and full characterization of novel 1,1′-difunctionalized ferrocene metalloligands is described. While one cyclopentadienyl ring has been functionalized with 2,2′-bipyridine for secondary coordination, the second Cp ring has been decorated wi
Palladium-catalyzed arylation of ferrocene derivatives: a convenient high yield route to 1,1'-bis(halophenyl)ferrocenes
Knapp, Ralf,Rehahn, Matthias
, p. 235 - 240 (2007/10/02)
The Pd-catalyzed cross-coupling reaction between halobenzenes and ferrocene-1,1'-diboronic acid is reported.Condensation proceeds smoothly to give 1,1'-diphenyl- and 1,1'-bis(halophenyl)-substituted ferrocenes bearing fluoro, chloro and bromo substituents in good yields.An effective synthesis of the intermediate ferrocene-1,1'-diboronic acid is described.
