32846-68-7Relevant articles and documents
Uneyama,Torii
, p. 367 (1972)
AN SRN1 APPROACH TO SOME AROMATIC NITRILES VIA DIAZOSULFIDES
Novi, Marino,Petrillo, Giovanni,Dell'Erba, Carlo
, p. 1345 - 1348 (2007/10/02)
Diazosulfides 1 react with excess tetrabutylammonium cyanide in Me2SO under photon (sunlamp) or electron (Pt cathode) stimulation to give the corresponding nitriles.The results are interpreted on the basis of an SRN1 mechanism involving the (phenylthio)azo as nucleofugal group.