10442-39-4Relevant articles and documents
Stereoselective addition of cyanide reagents to nitrones
Merchan, Francisco L.,Merino, Pedro,Tejero, Tomas
, p. 6949 - 6952 (1995)
An exploration of the diastereoselective addition of cyanide reagents to the nitrone 1 derived from D-glyceraldehyde acetonide to afford mixtures of syn-2 and anti-2 is presented. Trimethylsilyl cyanide was found to add to the nitrone 1 with essentially complete syn-stereoselectivity in excellent yields.
Syntheses and anion binding capabilities of bis(diarylboryl) ferrocenes and related systems
Kelly, Michael J.,Broomsgrove, Alexander E.J.,Morgan, Ian R.,Siewert, Inke,Fitzpatrick, Philip,Smart, Jessica,Vidovic, Dragoslav,Aldridge, Simon
, p. 2674 - 2684 (2013/06/26)
Isomeric diborylated ferrocenes featuring 1,1′-, 1,2-, and 1,3-substitution patterns have been targeted via a combination of electrophilic aromatic substitution and directed ortho-lithiation protocols. While none of these systems are competent for the Lewis acid chelation of fluoride, related systems featuring a mixed B/Si acceptor set capture 1 equiv of fluoride via a Si-F-B bridging motif.
Synthesis of a C3-symmetric furyl-cyclopeptide platform with anion recognition properties
Molina, Lidia,Moreno-Clavijo, Elena,Moreno-Vargas, Antonio J.,Carmona, Ana T.,Robina, Inmaculada
experimental part, p. 4049 - 4055 (2010/09/10)
A new furyl amino acid derivative was trimerized to give a linear peptide and finally was cyclized. The newly generated cyclopeptide was subjected to a conformational study in order to be considered as a C3-symmetric platform for the ratio nal design of complex receptors. Moreover, the recognition properties towards cyanide, acetate and chloride anions were studied.