32849-04-0Relevant academic research and scientific papers
SELECTIVE MONOESTERIFICATION OF UNPROTECTED MONO AND DISACCHARIDES
Bourhim, Abdellatif,Czernecki, Stanislas,Krausz, Pierre
, p. 853 - 863 (2007/10/02)
Under mild conditions, treatment of unprotected methyl-α-D-glucopyranoside, N-acetylglucosamine and maltose with triphenylphosphine, diethylazodicarboxylate and equimolar amount of various carboxylic acids allowed regioselective 6-O-esterifications (6'-O for maltose) of the carbohydrate without esterification of other hydroxyl groups.This reaction found an application in the synthesis of liposoluble, labelled sugars and hydrosoluble polymers.
