328555-15-3Relevant academic research and scientific papers
REACTION OF IODOBENZENE WITH TRIMETHYLTIN CYANIDE IN THE PRESENCE OF TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM: NEW COMPLEX FORMATION BETWEEN THE PALLADIUM AND THE CYANIDE
Kosugi, Masanori,Kato, Yasuki,Kiuchi, Kazuhiko,Migita, Toshihiko
, p. 69 - 72 (1981)
There were found to be another possible way producing benzonitrile in the reaction of PhI with Me3SnCN in the presence of Pd(PPh3)4, beside the ordinary one involving the oxidative addition of PhI to the Pd complex.Thus, the complexation of Pd complex with Me3SnCN gives a new complex n which reacts with PhI giving PhCN.This path is much faster than the former, but cannot make a catalytic cycle, because the palladium deposits during the reaction of the complex with PhI.
Phosphane-free palladium-catalyzed coupling reactions: The decisive role of Pd nanoparticles
Reetz, Manfred T.,Westermann, Elke
, p. 165 - 168 (2000)
Nanosized palladium colloids, generated in situ by reduction of Pd11 to Pd0 [Eq. (a)], are involved in the catalysis of phosphane-free Heck and Suzuki reactions with simple palladium salts such as PdCl2 or Pd(OAc)2, as demonstrated by transmission electron microscopic investigations.
Use of aromatic acid anhydrides as arylation agents in the heck reaction
Shmidt,Smirnov
, p. 743 - 744 (2008/10/08)
The use of bromide or chloride additives in styrene phenylation by benzoic acid anhydride results in an increase in catalytic activity and the yield of arylation products. The best results are obtained when LiCl is used. In this case, the yield of stilben
