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(ETHYL BENZOATE)TRICARBONYLCHROMIUM is a complex chemical compound formed by the combination of ethyl benzoate, an ester of benzoic acid used as a synthetic flavoring agent, and tricarbonylchromium, an organometallic compound used as a catalyst in organic synthesis. This unique structure and reactivity of the compound make it a promising candidate for applications in catalysis and organic chemistry.

32874-26-3

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32874-26-3 Usage

Uses

Used in Catalysis:
(ETHYL BENZOATE)TRICARBONYLCHROMIUM is used as a catalyst in various organic reactions for its ability to facilitate different organic transformations. Its unique structure and reactivity make it a potential candidate for improving the efficiency and selectivity of these reactions.
Used in Organic Chemistry Research:
(ETHYL BENZOATE)TRICARBONYLCHROMIUM is used as a research compound in the field of organic chemistry to explore its specific properties and potential applications. Ongoing studies aim to understand its reactivity and how it can be utilized in various chemical processes.
Used in Industrial Processes:
(ETHYL BENZOATE)TRICARBONYLCHROMIUM may have potential use in industrial processes due to its catalytic properties and ability to facilitate organic transformations. Its application in these processes is still being explored and researched to determine its full potential and benefits.
Note: The specific applications and industries for (ETHYL BENZOATE)TRICARBONYLCHROMIUM are still being explored and researched, as mentioned in the provided materials. The above uses are based on the general potential of the compound in catalysis and organic chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 32874-26-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,2,8,7 and 4 respectively; the second part has 2 digits, 2 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 32874-26:
(7*3)+(6*2)+(5*8)+(4*7)+(3*4)+(2*2)+(1*6)=123
123 % 10 = 3
So 32874-26-3 is a valid CAS Registry Number.
InChI:InChI=1/C9H10O2.3CHO.Cr/c1-2-11-9(10)8-6-4-3-5-7-8;3*1-2;/h3-7H,2H2,1H3;3*1H;/q;3*-1;+3

32874-26-3 Well-known Company Product Price

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  • Alfa Aesar

  • (44283)  (Ethyl benzoate)tricarbonylchromium, 98%   

  • 32874-26-3

  • 1g

  • 1105.0CNY

  • Detail
  • Alfa Aesar

  • (44283)  (Ethyl benzoate)tricarbonylchromium, 98%   

  • 32874-26-3

  • 5g

  • 5522.0CNY

  • Detail
  • Aldrich

  • (526738)  (Ethylbenzoate)tricarbonylchromium(0)  96%

  • 32874-26-3

  • 526738-2G

  • 2,558.79CNY

  • Detail

32874-26-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name carbon monoxide,chromium,ethyl benzoate

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:32874-26-3 SDS

32874-26-3Downstream Products

32874-26-3Relevant academic research and scientific papers

An improved method for the synthesis of η6-arenetricarbonylchromium complexes

Hudecek, Milan,Toma, Stefan

, p. 115 - 118 (2007/10/02)

A novel apparatus for the complexation of arenes with Cr(CO)6 is described.This, and the modification of the reaction procedure shortens the reaction time, and improves the yields of η6-arenetricarbonylchromium complexes.The method was tested f

Bis(aromat)chrom-Komplexe. Darstellung durch Cokondensation; IR-spektroskopische, cyclovoltammetrische und kinetische Untersuchungen

Brunner, Henri,Koch, Heinrich

, p. 65 - 83 (2007/10/02)

By cocondensation of Cr vapor, benzene and a substituted arene, in addition to bis(benzene)chromium(0), the compounds (arene)(benzene)chromium(0) (8a - 14a, 22a - 24a, 28a) and bis(arene)chromium(0) (15a - 21a, 25a - 27a, 29a) were synthesized.The complexes were oxidized to the corresponding bis(arene)chromium(I) iodides by titration with iodine solution.From the trend of the ν(C=O) frequencies in ester and keto substituents it follows that the (C6H6)Cr0 substituent is extremely electron donating, the (C6H6)CrI substituent, however, strongly electron withdrawing.In contrast, type and number of the substituents affect the redox potential Cr0/CrI irrespective of their arrangement at the bis(arene)chromium skeleton.The electron withdrawing character of the (C6H6)CrI-substituent is documented in a comparison of the base-catalyzed transesterification of free ang complexed methyl benzoate by rate differences of several powers of ten.The expected retardation of the transesterification of the corresponding chromium(0) complexes is outplayed by a chromium(I) catalysis.

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