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2,2,6,6-Tetramethyl-4-oxo-1-hydroxypiperidinium-perchlorate is a chemical compound with the molecular formula C9H18ClNO3. It is a derivative of piperidine, an alkaloid found in various plants, and is characterized by its four methyl groups (CH3) attached to the piperidine ring, a carbonyl group (C=O) at the 4-position, and a hydroxyl group (-OH) at the 1-position. The perchlorate ion (ClO4-) is present as a counterion, which is commonly used in organic chemistry to form salts with various cations. 2,2,6,6-Tetramethyl-4-oxo-1-hydroxypiperidinium-perchlorat is known for its potential use as a chiral catalyst in asymmetric synthesis, where it can help to control the stereochemistry of a reaction, leading to the preferential formation of one enantiomer over another. It is also of interest in the field of supramolecular chemistry due to its ability to form complexes with other molecules. The compound is typically synthesized through a series of chemical reactions and is used in research settings to explore its properties and potential applications.

32889-28-4

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32889-28-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 32889-28-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,2,8,8 and 9 respectively; the second part has 2 digits, 2 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 32889-28:
(7*3)+(6*2)+(5*8)+(4*8)+(3*9)+(2*2)+(1*8)=144
144 % 10 = 4
So 32889-28-4 is a valid CAS Registry Number.

32889-28-4Upstream product

32889-28-4Relevant academic research and scientific papers

Mechanism of disproportionation of 2,2,6,6-tetramethyl-1,4- dioxopiperidinium perchlorate in acidic aqueous medium

Golubev,Sen

, p. 1824 - 1827 (2009)

The cation of 2,2,6,6-tetramethyl-1,4-dioxopiperidinium perchlorate disproportionates in acidic aqueous medium to give piperidinoxyl and/or 1-hydroxypiperidine, nitrone, and acetone. A mechanism of this reaction was proposed and the rate constants for its particular steps were calculated.

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