32889-28-4Relevant articles and documents
Mechanism of disproportionation of 2,2,6,6-tetramethyl-1,4- dioxopiperidinium perchlorate in acidic aqueous medium
Golubev,Sen
, p. 1824 - 1827 (2009)
The cation of 2,2,6,6-tetramethyl-1,4-dioxopiperidinium perchlorate disproportionates in acidic aqueous medium to give piperidinoxyl and/or 1-hydroxypiperidine, nitrone, and acetone. A mechanism of this reaction was proposed and the rate constants for its particular steps were calculated.