329897-87-2

Upstream product

• 329897-85-0 Trifluoro-methanesulfonic acid (3S,3aS,4S,6aS,10R,10aR)-4-(tert-butyl-diphenyl-silanyloxymethyl)-3-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxy)-7,7-dimethyl-1-oxo-3,3a,4,6a,7,8,9,10-octahydro-2-oxa-cyclopenta[d]naphthalen-10-yl ester 
• 329897-84-9 (3S,3aS,4S,6aS,10aR)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-3-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxy)-7,7-dimethyl-3,3a,4,6a,7,8-hexahydro-2-oxa-cyclopenta[d]naphthalen-1-one 
• 248250-10-4 9-[(tert-butyl)(diphenyl)silanyloxy]-4,4-dimethylnona-5,7-dien-1-ol 
• 248250-11-5 (5E,7E)-9-(tert-Butyl-diphenyl-silanyloxy)-4,4-dimethyl-nona-5,7-dienal 
• 248250-09-1 tert-Butyl-((2E,4E)-6,6-dimethyl-nona-2,4,8-trienyloxy)-diphenyl-silane 
• 248250-07-9 (2E,4E)-6,6-Dimethyl-nona-2,4,8-trienoic acid methyl ester 
• 248250-08-0 (2E,4E)-6,6-dimethyl-2,4,8-nonatrien-1-ol 
• 5497-67-6 2,2-dimethyl-4-pentenal 
• 329897-86-1 (3S,3aS,4S,6aS,10aR)-4-Hydroxymethyl-3-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxy)-7,7-dimethyl-3,3a,4,6a,7,8-hexahydro-2-oxa-cyclopenta[d]naphthalen-1-one 
• 248250-13-7 (3S,3aS,4S,6aS,10R,10aR)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-10-hydroxy-3-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxy)-7,7-dimethyl-3,3a,4,6a,7,8,9,10-octahydro-2-oxa-cyclopenta[d]naphthalen-1-one 
• 248250-12-6 (S)-3-[(5E,7E)-(R)-9-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-4,4-dimethyl-nona-5,7-dienyl]-5-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxy)-5H-furan-2-one 

Relevant academic research and scientific papers

Synthetic studies towards mniopetals (II). A short synthesis of Mniopetal E

A short total synthesis of Mniopetal E in thirteen steps is reported. Key steps are a new and highly diastereoselective lithium phenylselenide induced Baylis-Hillman reaction with Feringa's butenolide, an endo-selective intramolecular Diels-Alder reaction (IMDA) and a new variant of the Parikh-Doering oxidation.