329977-96-0

Basic information

• Product Name: (1,1'-bis(diphenylphosphine)ferrocene)(phenylacetylenyl)platinum
• CAS NO: 329977-96-0
• Molecular Weight: 951.726
• Mol File: 329977-96-0.mol

Chemical Properties

• CAS DataBase Reference: (1,1'-bis(diphenylphosphine)ferrocene)(phenylacetylenyl)platinum(CAS DataBase Reference)
• NIST Chemistry Reference: (1,1'-bis(diphenylphosphine)ferrocene)(phenylacetylenyl)platinum(329977-96-0)
• EPA Substance Registry System: (1,1'-bis(diphenylphosphine)ferrocene)(phenylacetylenyl)platinum(329977-96-0)

Safety Data

• Hazardous Substances Data: 329977-96-0(Hazardous Substances Data)

Upstream product

• 104413-90-3 [1,1'-bis(diphenylphosphino)ferrocene]platinum(II) chloride 
• 536-74-3 phenylacetylene 
• 12150-46-8 1,1'-bis-(diphenylphosphino)ferrocene 

Relevant articles and documents

Synthesis, characterization and structural studies of new heterometallic alkynyl complexes of platinum and Group 11 metals with chelating bis(diphenylphosphino)ferrocene ligand

Reaction of the platinum bis(alkynyl) complex [Pt(dppf)(C ≡ CPh)2] (1) (dppf = bis(diphenylphosphino)ferrocene) with an equimolar amount of Group 11 metal salts [Cu(NCMe)4]BF4 and AgBF4 initially gives 1:1 mixed

Facile conversion of bis(alkynyl) into diyne ligand on platinum assisted by electrophilic gold phosphine

31P NMR spectroscopy measurements were used to establish the course for the stoichiometric-dependent reactions between [Au(PPh3)]+ and [Pt(C≡CPh)2(dppf)] (1), which for equimolar amounts afford as the unique product [Pt-{η3-C(C≡CPh)=C(Ph)Au(PPh3)}(dppf)] + (2), but any excess of 1 gives also [Pt(η2-PhC≡CC≡CPh)(dppf)] (3) [dppf = 1,1′-bis(diphenylphosphine)ferrocene]. Both compounds 2 and 3 were obtained straightforwardly by the reactions of 3 with [Au(PPh3)]+ and [Pt(C2H4)(dppf)] with 1,4-diphenylbutadiyne, respectively. The X-ray crystal structure analysis of 3 confirmed a trigonal-planar coordination geometry about the platinum atom, and a bent η2-coordinated diyne ligand.