3302-87-2

Basic information

• Product Name: 1-phenylphospholane
• Synonyms: Phospholane, 1-phenyl-
• CAS NO: 3302-87-2
• Molecular Formula: C₁₀H₁₃P
• Molecular Weight: 164.184
• Mol File: 3302-87-2.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 255°C at 760 mmHg
• Flash Point: 111.4°C
• Vapor Pressure: 0.0268mmHg at 25°C
• CAS DataBase Reference: 1-phenylphospholane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylphospholane(3302-87-2)
• EPA Substance Registry System: 1-phenylphospholane(3302-87-2)

Safety Data

• Hazardous Substances Data: 3302-87-2(Hazardous Substances Data)

Usage

Type of compound

Phosphorus-based

Structure

Contains a phospholane ring with a phenyl group attached

Use as a ligand

Utilized in organometallic chemistry for catalyzing various reactions

Potential applications

Asymmetric hydrogenation, catalytic processes, synthesis of pharmaceuticals, and other fine chemicals

Interest

Versatility and effectiveness as a catalyst in organic synthesis

Upstream product

• 13595-56-7 dilithium phenylphosphide 
• 110-56-5 1,4-dichlorobutane 
• 52054-23-6 diethyl-phospholan-1-yl-amine 
• 110-52-1 1,4-dibromo-butane 
• 644-97-3 Dichlorophenylphosphine 
• 703-03-7 1-phenyl-2-phospholene-1-oxide 
• 52988-62-2 1-phenyl-2-phospholen-1-sulfide 
• 4963-90-0 1-Phenylphospholane 1-sulfide 
• 5186-73-2 1-phenyl-3-phospholene 1-oxide 
• 377764-13-1 1-phenylphospholane-borane 
• 4963-85-3 but-3-enyl-phenyl-phosphane 

Downstream Products

• 114306-38-6 1-amino-1-phenyl-phospholanium; chloride 
• 377764-13-1 1-phenylphospholane-borane 
• 192328-89-5 dichlorobis(1-phenylphospholane)palladium(II) 
• 926277-26-1 trans-[RhCl(CO)(1-phenylphospholane)2] 
• 192328-88-4 bis(acetato)bis(1-phenylphospholane)palladium(II) 
• 4963-90-0 1-Phenylphospholane 1-sulfide 
• 4963-91-1 1-phenylphospholane-1-oxide 
• 3302-93-0 1-methyl-1-phenyl-phospholanium; iodide 
• 28860-47-1 N-(1-phenyl-1λ⁵-phospholan-1-ylidene)-benzamide 

Relevant articles and documents

Synthesis of a new chiral source, (1R,2S)-1-phenylphospholane-2-carboxylic acid, via a key intermediate α-phenylphospholanyllithium borane complex: Configurational stability and X-ray crystal structure of an α- monophosphinoalkyllithium borane complex

A synthetic route to enantiomerically pure (1R,2S)-1-phenylphos-pholane-2- carboxylic acid (1), which is a phosphorus analogue of proline, has been established. A key step is the deprotonation-carboxylation of the 1-phenylphospholane borane complex 3 by u

Raney-Ni reduction of phosphine sulfides

A variety of tertiary phosphine sulfides have been reduced by Raney-Ni to give the corresponding phosphineswith high efficiency and undermild conditions. Alkyl, aryl, acyclic, cyclic, aswell as sterically crowded phosphine sulfides are reduced with equal facility. Optically active P-stereogenic phosphine sulfides are reduced stereospecifically with clean retention of configuration at P. Reductions of unsaturated phosphinesulfides is not fully chemoselective and takes place with concomitant partial reduction of the double bond. Clean reduction of the unsaturated phosphine sulfides to the corresponding fully saturated phosphines can be achieved in one step by running the reduction under H2atmosphere (balloon).

Cyclic phosphonium ionic liquids

Ionic liquids (ILs) incorporating cyclic phosphonium cations are a novel category of materials. We report here on the synthesis and characterization of four new cyclic phosphonium bis(trifluoromethylsulfonyl)amide ILs with aliphatic and aromatic pendant g