33038-70-9

Upstream product

• 7601-90-3 perchloric acid 
• 64-17-5 ethanol 
• 770-34-3 benzyl(isopropyl)sulfane 
• 7722-84-1 dihydrogen peroxide 
• 911820-11-6 3-(isopropylsulfinyl)propionic acid tert-butyl ester 
• 108-88-3 toluene 
• 72054-32-1 methyl phenylmethanesulfinate 
• 920-39-8 isopropylmagnesium bromide 

Downstream Products

• 252228-48-1 C₁₀H₁₅NOS 
• 189881-43-4 (C₅H₅)Ru((C₆H₅)2PCH₂P(C₆H₅)2)(C₆H₅CH₂S(O)CH(CH₃)2)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru((C₆H₅)2PCH₂P(C₆H₅)2)(C₆H₅CH₂S(O)CH(CH₃)2)]PF₆ 
• 189881-47-8 (C₅H₅)Ru((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(C₆H₅CH₂S(O)C₃H₇)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(C₆H₅CH₂S(O)C₃H₇)]PF₆ 
• 189958-89-2 [Cp((2-(dimethylphosphino)ethyl)diphenylphosphine)Ru(BzS(O)-i-Pr)]PF₆ 

Relevant academic research and scientific papers

Nondirected Copper-Catalyzed Sulfoxidations of Benzylic C-H Bonds

A copper-catalyzed sulfoxidation of benzylic C-H bonds by nondirected oxidative C(sp3)-H activation was developed. The process proceeds via sulfenate anions, which are generated by base-triggered elimination of β-sulfinyl esters and benzyl radicals. The functional group tolerance is high, and the product yields are good.

Selective and efficient oxidation of sulfides to sulfoxides with N-bromosuccinimide in the presence of β-cyclodextrin in water

A simple and highly selective oxidation of sulfides to sulfoxides with N-bromosuccinimide (NBS) catalyzed by β-cyclodextrin in water has been developed. A series of sulfides were oxidized selectively at room temperature in excellent yields. This reaction