330476-89-6Relevant articles and documents
Synthesis of pyranoid and furanoid glycals from glycosyl sulfoxides by treatment with organolithium reagents
Gomez, Ana M.,Casillas, Marta,Barrio, Aitor,Gawel, Anna,Lopez, J. Cristobal
experimental part, p. 3933 - 3942 (2009/04/08)
Glycosyl sulfoxides can be conveniently transformed into pyranoid or furanoid glycals by treatment with organolithium reagents. The more likely reaction pathway involves a sulfoxide/metal exchange reaction to generate a glycosyllithium derivative that und