62327-60-0Relevant academic research and scientific papers
Facile Diastereoseparation of Glycosyl Sulfoxides by Chiral Stationary Phase
Taniguchi, Tohru,Asahata, Mai,Nasu, Akihito,Shichibu, Yukatsu,Konishi, Katsuaki,Monde, Kenji
supporting information, p. 534 - 539 (2016/07/28)
Separation of the diastereomers of glycosyl sulfoxides differing in the sulfur chirality has been difficult. This article presents a fast and scalable method for their diastereoseparation using a chiral stationary phase. The usefulness of this method was
Synthesis of pyranoid and furanoid glycals from glycosyl sulfoxides by treatment with organolithium reagents
Gomez, Ana M.,Casillas, Marta,Barrio, Aitor,Gawel, Anna,Lopez, J. Cristobal
experimental part, p. 3933 - 3942 (2009/04/08)
Glycosyl sulfoxides can be conveniently transformed into pyranoid or furanoid glycals by treatment with organolithium reagents. The more likely reaction pathway involves a sulfoxide/metal exchange reaction to generate a glycosyllithium derivative that und
PHOTOINDUCED GENERATION OF GLYCOSYL CATIONS FROM THIOGLYCOSIDES
Griffin, Gary W.,Bandara, Nayanie C.,Clarke, Margaret A.,Tsang, Wing-Sum,Garegg, Per J.,et al.
, p. 939 - 947 (2007/10/02)
Photochemically induced cleavage of thioaryl β-D-glucopyranosides using 1,4-dicyanonaphthalene as an electron-transfer agent, produces glycosyl cations potentially useful in glycosylation reactions.
