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2H-1,3-Thiazine-5-carbonitrile, 3,4-dihydro-6-(methylthio)-4-oxo-2-phenyl- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

33050-23-6

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33050-23-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 33050-23-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,3,0,5 and 0 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 33050-23:
(7*3)+(6*3)+(5*0)+(4*5)+(3*0)+(2*2)+(1*3)=66
66 % 10 = 6
So 33050-23-6 is a valid CAS Registry Number.

33050-23-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 5-cyano-6-(methylthio)-2-phenyl-2,3-dihydro-1,3-thiazin-4-one

1.2 Other means of identification

Product number -
Other names 4H-5-Cyano-2,3-dihydro-6-methylthio-2-phenyl-1,3-thiazin-4-on

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:33050-23-6 SDS

33050-23-6Relevant academic research and scientific papers

S,N Double Rearrangement. 2. X-ray Crystal Structures of Rearranged Products

Yokoyama, Masataka,Nakamura, Masaki,Ohteki, Hiroko,Imamoto, Tsuneo,Yamaguchi, Kei-ichi

, p. 1090 - 1094 (2007/10/02)

Condensation of 2-cyano-3-mercapto-3-(methylthio)acrylamide (1) with benzoic acid in the presence of polyphosphate ester gave 5-carbamoyl-4-(methylthio)-2-phenyl-1,3-oxazine-6-thione (6), which, on treatment with boiling ethanol, was easily converted into 5-carbamoyl-4-(methylthio)-2-phenyl-1,3-thiazin-6-one (9).Reduction of 9 with NaBH4 gave its 2,3-dihydro derivative 10.The strucures of 6,9, and 10 were determined by single-crystal X-ray diffraction.A reaction mechanism of this novel S,N double rearrangement is briefly discussed.

A Novel S,N-Double Rearrangement; X-Ray Crystal Structure of 5-Carbamoyl-4-methylthio-2-phenyl-1,3-thiazin-6-one and Its 2,3-Dihydro-derivative

Yokoyama, Masataka,Nakamura, Masaki,Imamoto, Tsuneo,Yamaguchi, Kei-ichi

, p. 560 - 561 (2007/10/02)

Condensation of 2-cyano-3-mercapto-3-(methylthio)acrylamide (1) with benzoic acid in the presence of polyphosphate ester gave 5-carbamoyl-4-methylthio-2-phenyl-1,3-thiazin-6-one (5); the structures of (5) and its 2,3-dihydro-derivative (6) were determined

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