330596-36-6

Upstream product

• 302783-17-1 methyl 2,3-di-O-acetyl-4,6-O-p-methoxybenzylidene-α-D-glucopyranoside 

Downstream Products

• 870001-84-6 (2S,3S,4S,5R,6S)-4,5-Diacetoxy-6-methoxy-3-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-carboxylic acid 
• 604-70-6 Acetic acid (2R,3R,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-methoxy-tetrahydro-pyran-4-yl ester 
• 330596-40-2 [4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester 
• 330596-35-5 (4-Hydroxymethyl-2-nitro-phenoxy)-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester 
• 330596-39-9 [4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-hydroxy-6-methoxy-tetrahydro-pyran-2-ylmethyl ester 
• 870001-64-2 methyl (methyl 4-O-[2-azido-6-O-(tert-butyldiphenylsilyl)-2-deoxy-3-O-levulinoyl-4-O-(p-methoxybenzyl)-α-D-glucopyranosyl]-2-O-acetyl-3-O-[2-(trimethylsilyl)ethoxymethyl]-α-D-glucopyranosyluronate) 
• 870001-90-4 3-[3-azido-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-(4-methoxy-benzyloxy)-4-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-yloxy]-5-hydroxy-6-methoxy-4-(2-trimethylsilanyl-ethoxymethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 870001-89-1 (2S,3S,4S,5R,6S)-5-Acetoxy-3-[(2R,3R,4R,5S,6R)-3-azido-6-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-5-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-6-methoxy-4-(2-trimethylsilanyl-ethoxymethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 870001-88-0 (2S,3S,4S,5R,6S)-5-Acetoxy-3-[(2R,3R,4R,5S,6R)-3-azido-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-hydroxy-4-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-yloxy]-6-methoxy-4-(2-trimethylsilanyl-ethoxymethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 870001-86-8 (2S,3S,4S,5R,6S)-5-Acetoxy-3-[(2R,3R,4R,5S,6R)-3-azido-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-(4-methoxy-benzyloxy)-4-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-yloxy]-4-hydroxy-6-methoxy-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 870001-67-5 (2S,3S,4S,5R,6S)-5-Acetoxy-3-[(2R,3R,4R,5S,6R)-3-azido-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-(4-methoxy-benzyloxy)-4-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-yloxy]-4-hydroxy-6-methoxy-tetrahydro-pyran-2-carboxylic acid 
• 870001-91-5 (2S,3S,4S,5R,6S)-5-Acetoxy-3-[(2R,3R,4R,5S,6R)-3-amino-6-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-5-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-6-methoxy-4-(2-trimethylsilanyl-ethoxymethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 870001-87-9 (2S,3S,4S,5R,6S)-5-Acetoxy-3-[(2R,3R,4R,5S,6R)-3-azido-6-hydroxymethyl-5-(4-methoxy-benzyloxy)-4-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-yloxy]-6-methoxy-4-(2-trimethylsilanyl-ethoxymethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 870001-85-7 methyl 2-O-acetyl-4-(p-methoxybenzyl)-α-D-3,6-glucuronolactone 

Relevant academic research and scientific papers

A new phenoxyacetate-based linker system for the solid-phase synthesis of oligosaccharides.

[structure: see text]. A novel linker system has been designed, and its first application to solid-phase oligosaccharide synthesis is described. The use of the highly reactive o-nitro-phenoxyacetate linker allows a fast and quantitative cleavage using mild basic conditions. This method combined with the trichloroacetimidate glycosylation exhibits highly promising results as demonstrated for the synthesis of tetrasaccharide 1 (n = 3) containing glucose beta(1 --> 4) and beta(1 --> 6) linkages.

Cyanuric chloride/sodium borohydride: A new reagent combination for reductive opening of 4,6-benzylidene acetals of carbohydrates to primary alcohols

In the first such example, NaBH4 in combination with cyanuric chloride (TCT) has been used to obtain 6-hydroxy-4-benzyl ether derivatives from 4,6-benzylidene acetals of carbohydrates. The nature of hydride donor determines the regioselectivity

Orthogonal sulfation strategy for synthetic heparan sulfate ligands

(Chemical Equation Presented) An orthogonal sulfation strategy involving six different protecting groups has been developed for generating sulfated carbohydrate libraries based on heparan. Chemoselective cleavage conditions (optimized for a heparan disacc