33065-93-9Relevant academic research and scientific papers
ADDITION OF BROMINE GAS TO CRYSTALLINE DIBENZOBARRELENE: AN ENANTIOSELECTIVE CARBOCATION REARRANGEMENT IN THE SOLID STATE
Garcia-Garibay, Miguel,Scheffer, John R.,Trotter, James,Wireko, Fred
, p. 1485 - 1488 (1988)
Treatment of chiral crystals of 2,3:5,6-dibenzobicycloocta-2,5,7-triene (dibenzobarrelene, 1) with bromine vapor results in the formation of the rearranged product syn-8-bromo-endo-4-bromo2,3:6,7-dibenzobicycloocta-2,6-diene (2) in up to 8percent enantiomeric excess.
