Tetrahedron Letters p. 1485 - 1488 (1988)
Update date:2022-08-05
Topics:
Garcia-Garibay, Miguel
Scheffer, John R.
Trotter, James
Wireko, Fred
Treatment of chiral crystals of 2,3:5,6-dibenzobicyclo<2,2,2>octa-2,5,7-triene (dibenzobarrelene, 1) with bromine vapor results in the formation of the rearranged product syn-8-bromo-endo-4-bromo2,3:6,7-dibenzobicyclo<3,2,1>octa-2,6-diene (2) in up to 8percent enantiomeric excess.
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Doi:10.1016/j.cclet.2021.02.032
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