33070-47-2Relevant academic research and scientific papers
Ring closure reactions of β-nitroso-, β-acyl-, and β-thiocarbamoyl-α,β-unsaturated sulfilimines. Synthesis of [1,2,5]oxadiazolo[3,4-d]-, isoxazolo[3,4-d]-, and isothiazolo[3,4-d]pyrimidine derivatives from uracils
Matsumoto, Nobuaki,Takahashi, Masahiko
, p. 10073 - 10079 (2007/10/03)
1,3-Dialkyl-6-chlorouracils were treated with S,S-diphenylsulfilimine to give N-(1,3-dialkyluracil-6-yl)-S,S-diphenylsulfilimines. The uracilylsulfilimines were nitrosated, acylated, or thiocarbamoylated to give N-(5-nitroso-, 5-acyl-, or 5-thiocarbamoyluracil-6-yl)sulfilimines, respectively. These conjugated sulfilimines were cyclized by thermolysis or photolysis to [1,2,5]oxadiazolo[3,4-d], isoxazolo[3,4-d], or isothiazolo[3,4-d]pyrimidine derivatives.
Convenient and versatile synthetic methods for furazano[3,4-d]pyrimidines
Sako,Oda,Hirota,Beardsley
, p. 1255 - 1257 (2007/10/03)
Treatment of the readily available 6-amino-5-nitrosopyrimidines with a slight excess of iodobenzene diacetate or N-iodosuccinimide in anhydrous DMF containing three equivalents of lithium hydride at ambient temperature resulted in the smooth and versatile
Mechanistic Aspects of the Oxidation of 1,3-Disubstituted 6-Amino-5-nitrosouracils with Lead Tetraacetate: The Formation of Pyrimidopteridinetetrone 10-Oxides
Sako, Magoichi,Ohara, Seiji,Hirota, Kosaku,Kano, Keuji,Maki, Yoshifumi,Taylor, Edward C.
, p. 6302 - 6306 (2007/10/02)
Lead tetraacetate oxidation of 1,3-disubstituted 6-amino-5-nitrosouracils 1 in glacial acetic acid results in the formation of 1,3,6,8-tetrasubstituted pyrimidopteridine-2,4,5,7(1H,3H,6H,8H)-tetrone 10-oxides 2.ESR studies and a number of chemical
A CONVERSION OF OXADIAZOLOPYRIMIDINE 1-OXIDES INTO PURINES
Yoneda, Fumio,Tachibana, Takako,Tanoue, Junko,Yano, Tetsumi,Sakuma, Yoshiharu
, p. 341 - 344 (2007/10/02)
Treatment of oxadiazolopyrimidine 1-oxides with amines led to the formation of the corresponding 8-substituted purine derivatives, along with other heterocyclic compounds in some cases.
