330800-07-2Relevant academic research and scientific papers
Chiral phosphine-phosphonium ylide rhodium complexes
Viau, Lydie,Lepetit, Christine,Commenges, Gérard,Chauvin, Remi
, p. 808 - 810 (2001)
The phosphonium methylide of (R)-BINAP acts as a novel chiral dissymmetric chelating ligand in the stable [Rh(cod)(BINAPCH2)]+ complex. A rationale for the conformation of the eight-membered metallacycle derived from chiral phosphine-phosphonium ylide ligands is proposed on the basis of DFT calculations on a model complex.
