331-04-4Relevant academic research and scientific papers
Chemoenzymatic dynamic kinetic resolution of primary amines catalyzed by CAL-B at 38-40°c
Poulhes, Florent,Vanthuyne, Nicolas,Bertrand, Michele P.,Gastaldi, Stephane,Gil, Gerard
body text, p. 7281 - 7286 (2011/10/10)
The (R)-selective chemoenzymatic dynamic kinetic resolution of primary amines was performed at 38-40 °C in MTBE, in good to high yields and with high enantiomeric excesses. These reactions associating CAL-B to octanethiol as radical racemizing agent were carried out in the presence of methyl β-methoxy propanoate as acyl donor, under photochemical irradiation at 350 nm in glassware.
Highly efficient photochemically induced thiyl radical-mediated racemization of aliphatic amines at 30 °C
Routaboul, Lucie,Vanthuyne, Nicolas,Gastaldi, Stephane,Gil, Gerard,Bertrand, Michele
, p. 364 - 368 (2008/09/17)
(Chemical Equation Presented) UV irradiation in the presence of thiol enables the performance of highly efficient aliphatic amines racemization, under mild conditions at 30°C. The reaction proceeds via the reversible generation of prochiral α-aminoalkyl r
Phenethylamine antigenic conjugates, their preparation, antibodies, and use
-
, (2008/06/13)
Antigenic phenethylamine conjugates are produced by blocking the amine of the phenethylamine hapten with a group, coupling of the phenethylamine to a carrier, and removal of the blocking group. Specific phenethylamines useful in this invention are ampheta
Phenethylamine antigenic conjugates, their preparation, antibodies and use
-
, (2008/06/13)
Antigenic phenethylamine conjugates are produced by blocking the amine of the phenethylamine hapten with a group, coupling of the phenethylamine to a carrier, and removal of the blocking group. Specific phenethylamines useful in this invention are ampheta
