3310-63-2

Upstream product

• 959-31-9 dibenzoyldiazene 
• 1165952-91-9 cyclohexa-1,3-diene 
• 98-88-4 benzoyl chloride 
• 124020-67-3 4-Methyl-2,4,6-triaza-tricyclo[5.2.2.0^2,6]undeca-8,10-diene-3,5-dione 
• 78790-57-5 2-methyl-4,5,8,9-tetrahydro-5,8-ethano[1,2,4]triazolo[1,2-a]pyridazine-1,3-dione 

Downstream Products

• 14554-59-7 1-benzoyl-3-phenyl-(4ar,8ac)-4a,5,6,7,8,8a-hexahydro-1H-benzo[1,3,4]oxadiazine 
• 38154-53-9 1-benzoyl-3-phenyl-(4ar,8ac)-4a,7,8,8a-tetrahydro-1H-benzo[1,3,4]oxadiazine 

Relevant academic research and scientific papers

Arenophile-Mediated Dearomative Reduction

A dearomative reduction of simple arenes has been developed which employs a visible-light-mediated cycloaddition of arenes with an N-N-arenophile and in situ diimide reduction. Subsequent cycloreversion or fragmentation of the arenophile moiety affords 1,3-cyclohexadienes or 1,4-diaminocyclohex-2-enes, compounds that are not synthetically accessible using existing dearomatization reactions. Importantly, this strategy also provides numerous opportunities for further derivatization as well as site-selective functionalization of polynuclear arenes.

Stereospecific synthesis of cyclic hydrazoacetic acids and meso- diaminodicarboxylic acids

The hetero Diels-Alder adducts 6a - d derived from azodibenzoyl and cyclic dienes were oxidized by ruthenium tetroxide and transformed into meso- diaminodicarboxylic acids 12a - d via the new cyclic hydrazoacetic acids 9a - d.