33131-14-5

Basic information

• Product Name: 2(5H)-Furanone, 4-methyl-3-phenyl-
• CAS NO: 33131-14-5
• Molecular Formula: C11H10O2
• Molecular Weight: 174.199
• Mol File: 33131-14-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2(5H)-Furanone, 4-methyl-3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2(5H)-Furanone, 4-methyl-3-phenyl-(33131-14-5)
• EPA Substance Registry System: 2(5H)-Furanone, 4-methyl-3-phenyl-(33131-14-5)

Safety Data

• Hazardous Substances Data: 33131-14-5(Hazardous Substances Data)

Upstream product

• 673-32-5 1-Phenylprop-1-yne 
• 201230-82-2 carbon monoxide 
• 103-82-2 phenylacetic acid 
• 78-95-5 chloroacetone 
• 129313-31-1 (+/-)-(2S^*,3S^*)-2,3-Epoxy-2-methyl-3-phenylpropan-1-ol 
• 74-88-4 methyl iodide 
• 31491-21-1 2-phenyl-1,1-bis(trimethylsilyloxy)ethene 
• 243861-05-4 2-methoxycarbonyl-3-phenyl-butanedioic acid-4-tert-butyl-1-methyl ester 
• 35132-16-2 tert-butyl α-bromo-α-phenylacetate 
• 168475-91-0 6a-Phenyl-3a,6a-dihydro-3H-furo[3,4-c]pyrazole-4,6-dione 
• 243861-06-5 2-methoxycarbonyl-3-phenyl-butanedioic acid 

Downstream Products

• 1210328-02-1 C₂₂H₂₀O₄ 
• 129266-28-0 (S)-2-Hydroxy-2-((S)-3-methyl-5-oxo-4-phenyl-2,5-dihydro-furan-2-yl)-propionic acid 

Relevant articles and documents

Carbonylation of Acetylenes under Water Gas Shift Conditions: A New Method for Synthesis of Furan-2(5H)-ones

Under water gas shift conditions acetylenes are selectively converted into furan-2(5H)-ones with catalysis by rhodium carbonyl clusters.

Furan-2(3H)- and -2(5H)-ones. Part 6. Di-?-methane rearrangement of the α-substituted 4-benzylfuran-2(5H)-one system

The effect of the 'central methane' substitution on the di-?-methane rearrangement in 4-benzyl-2,5-dihydrofuran-2-ones 8a-d was investigated.Significant enhancement of efficiency in the rearrangement leading in high combined yields to two isomeric products, endo-12 and exo-12, is discussed in terms of both the substituent effects at the benzylic carbon and the restrained features of the ring-enrolled ?-system.The origin of the difference in chemoselectivity compared with that of the 3-benzyl counterpart 5 where a photoarylated product 6 resulted upon photoirradiation was also investigated, and was rationalized by postulating a higher reactivity at the β-position of the enone system.

The remarkable cobalt- and phase-transfer-catalyzed carbonylation of epoxy alcohols: A formal triple carbonylation reaction

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