331456-61-2

Upstream product

• 20452-28-2 phenyl 1-thio-β-D-xylopyranoside 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 1092981-95-7 1-deoxy-2,3,4-tris-O-(tert-butyldimethylsilyl)-1-[(Ss)-phenylsulfinyl]-β-D-xylopyranoside 
• 432038-18-1 (2S,4R,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-4-[(Z)-2-(tert-butyl-dimethyl-silanyl)-pentadec-1-enyl]-2-phenyl-[1,3]dioxane 
• 432038-19-2 (2S,4R,5R)-4-[(Z)-2-(tert-Butyl-dimethyl-silanyl)-pentadec-1-enyl]-2-phenyl-[1,3]dioxan-5-ol 
• 331456-63-4 1,5-Anhydro-3,4-bis-O-(tert-butyldimethylsilyl)-2-deoxy-1-phenylsulfonyl-D-threo-pent-1-enitol 
• 114275-39-7 (2R,3R,4E)-1,3-benzylidene-4-octadecene-1,2,3-triol 
• 114275-40-0 (2R,3R)-trans-2-azide-1,3-O-benzylidene-1,3-octadec-4-enediol 
• 103348-49-8 2-azido-sphingosine 
• 123-78-4 (2S,3R,4E)-2-amino-4-octadecene-1,3-diol 
• 54336-64-0 (2S,3R,4E)-2-(N-stearoylamino)-4-octadecene-1,3-diol 
• 331456-62-3 2,3,4-Tris-O-(tert-butyldimethylsilyl)-β-D-xylopyranosyl phenyl sulfone 

Relevant academic research and scientific papers

Synthesis of phalluside-1 and Sch II using 1,2-metallate rearrangements

(4E,8E,10E)-9-Methyl-4,8,10-sphingatrienine, a core component of marine sphingolipids, was synthesised for the first time using a copper(i)-mediated 1,2-metallate rearrangement of a lithiated glycal as a key step. It was converted to phalluside-1, a cereb

The preparation of 1-tributylstannyl glycals from 1-phenylsulfonyl glycals via Ni(0)-catalysed coupling with tributylstannylmagnesium bromide

1-Phenylsulfonyl glycals undergo an easy Ni(0)-catalysed coupling with tributylstannylmagnesium bromide to give the corresponding 1-tributylstannyl glycals in good yield.