331463-16-2

Basic information

• Product Name: (dichloro-fluoro-methanesulfonyl)-benzene
• Synonyms: (dichloro-fluoro-methanesulfonyl)-benzene
• CAS NO: 331463-16-2
• Molecular Weight: 243.086
• Mol File: 331463-16-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (dichloro-fluoro-methanesulfonyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (dichloro-fluoro-methanesulfonyl)-benzene(331463-16-2)
• EPA Substance Registry System: (dichloro-fluoro-methanesulfonyl)-benzene(331463-16-2)

Safety Data

• Hazardous Substances Data: 331463-16-2(Hazardous Substances Data)

Upstream product

• 882-33-7 diphenyldisulfane 
• 130755-47-4 (dichlorofluoromethyl)(phenyl)sulfide 

Downstream Products

• 20808-12-2 fluoromethyl phenyl sulfone 
• 140243-94-3 1-chloro-1-fluoromethyl phenyl sulfone 
• 331463-24-2 1-chloro-1-fluoro-1-phenylsulfonyl-2-heptanol 
• 331463-26-4 1-chloro-1-fluoro-1-phenylsulfonyl-4-methyl-2-pentanol 
• 5433-76-1 diphenylmethyl phenyl sulfone 
• 19523-24-1 1-methyl-4-((phenylsulfonyl)methyl)benzene 
• 3112-88-7 Benzyl phenyl sulfone 

Relevant articles and documents

Chemistry of trichlorofluromethane: Synthesis of chlorofluromethyl phenyl sulfone and fluoromethyl phenyl sulfone and some of their reactions

It was observed that the reaction of CFCl3 with thiophenoxide gave only 10% of the corresponding thioether. On the other hand, these thioethers could be prepared in excellent yield from diaryl disulfides and CFCl3 in the presence of sodium hydroxymethanesulfinate in aqueous DMF at 4 atm pressure of nitrogen. Dechlorination of the thioether (PhSCFCl2) with different reducing agents were studied. Most of the reducing agents eliminated both fluorine and chlorine functionalities or gave the hydrolyzed products. But its sulfone on treatment with Zinc in methanol gave monochlorofluoromethyl and fluoromethyl phenyl sulfone in good yields. Darzens reaction of these compounds was also studied.