33148-49-1Relevant academic research and scientific papers
Facile conversion of dithioesters into carboxylic acids or esters using alkaline hydrogen peroxide
Grellepois, Fabienne,Portella, Charles
experimental part, p. 3443 - 3446 (2009/05/09)
Simple, mild, and environmentally friendly procedures for the direct conversion of dithioesters into either carboxylic acids or esters using hydrogen peroxide under alkaline conditions are described. Georg Thieme Verlag.
Mild method for the conversion of amides to thioamides
Charette, Andre B.,Grenon, Michel
, p. 5792 - 5794 (2007/10/03)
Aqueous ammonium sulfide was found to be an ideal substitute for hydrogen sulfide for the thiolysis of activated amides. High yields of the corresponding thioamides were obtained for a broad range of substrates, using two different procedures that are both operationally simple and inexpensive, as well as amenable to large-scale preparation. Preliminary results indicate that aqueous ammonium sulfide may also replace hydrogen sulfide in the synthesis of thionoesters from amides.
