33148-54-8Relevant academic research and scientific papers
Trifluoroacetic acid catalyzed dibenzodiazocine synthesis: Optimization and mechanism study
Zhao, Na,Qiu, Li,Wang, Xiao,Li, Jianzhong,Jiang, Yi,Wan, Xiaobo
, p. 9665 - 9671,7 (2020/08/20)
Dibenzo[b,f][1,5]diazocines, a class of potential building blocks for novel electrochemical actuators, were synthesized via a novel, efficient acid-catalyzed reaction of 2-acylbenzoisocyanate at room temperature. Real-time NMR analysis and the captured intermediate showed the mechanism was an unprecedented cyclization of the isocyanate with the neighboring acyl group, followed by the dimerization.
Ring-chain tautomerism. Part 10 +. The reaction of oxocarboxylic acids with diazodiphenylmethane
Bowden, Keith,Misic-Vukovic, Milica M.,Ranson, Richard J.
, p. 1601 - 1606 (2007/10/03)
The rate coefficients for the esterification of a series of oxocarboxylic acids with diazodiphenylmethane have been determined in ethanol or 2-methoxyethanol at 30.0°C. These and the rates of reaction with model compounds have been used to estimate the equilibrium constants for ring-chain tautomerism for the oxocarboxylic acids.
