331765-84-5Relevant academic research and scientific papers
The scope and limitation of the [1,4]-SPh shift in the synthesis of allylic alcohols
Aggarwal, Varinder K.,Eames, Jason,De Las Heras, Maria A.,McIntyre, Sara,Warren, Stuart
, p. 4456 - 4461 (2000)
Treatment of a series of 4-phenylsulfanyl-1,3-diols with toluene-p-sulfonyl chloride in pyridine gives stereospecifically substituted allylic alcohols in near quantitative yield via a [1,4]-SPh shift. We comment on the structural variation at both the mig
