57768-35-1

Basic information

• Product Name: Cyclohexanecarboxaldehyde, 1-(phenylthio)-
• CAS NO: 57768-35-1
• Molecular Formula: C13H16OS
• Molecular Weight: 220.335
• Mol File: 57768-35-1.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Cyclohexanecarboxaldehyde, 1-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarboxaldehyde, 1-(phenylthio)-(57768-35-1)
• EPA Substance Registry System: Cyclohexanecarboxaldehyde, 1-(phenylthio)-(57768-35-1)

Safety Data

• Hazardous Substances Data: 57768-35-1(Hazardous Substances Data)

Upstream product

• 21849-30-9 2-benzenesulfinyl-1-oxa-spiro[2.5]octane 
• 930-69-8 sodium thiophenolate 
• 2043-61-0 cyclohexanecarbaldehyde 
• 13865-50-4 methoxymethyl phenyl sulfide 
• 13307-57-8 α-Hydroxy-cyclohexancarbaldehyd-diphenylthioacetal 
• 53282-55-6 (trimethylsiloxymethylidene)cyclohexane 
• 931-59-9 benzenesulfenyl chloride 
• 139058-74-5 1-(diacetoxymethyl)-1-(phenylsulfenyl)cyclohexane 
• 75456-59-6 1--1-cyclohexanol 
• 882-33-7 diphenyldisulfane 

Downstream Products

• 139747-29-8 3-[Hydroxy-(1-phenylsulfanyl-cyclohexyl)-methyl]-dihydro-furan-2-one 
• 104750-38-1 (2RS,3SR)-2,6-dimethylphenyl 3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propionate 
• 138649-97-5 (4S)-3-<(2S,3S)-3-hydroxy-2-methyl-1-oxo-3-(1-phenylsulfanylcyclohexyl)propyl>-4-phenylmethyl-1,3-oxazolidin-2-one 
• 135967-29-2 4-(1''-Ethoxyethoxy)-1-[1'-(phenylsulfanyl)cyclohexyl]butanol 
• 81650-72-8 [1-(Phenylsulfanyl)cyclohexyl]ethene 
• 165748-29-8 2-[1'-(Phenylsulfanyl)cyclohexyl]epoxyethane 
• 253152-05-5 Ethyl 3-hydroxy-3-[1'-(phenylsulfanyl)cyclohexyl]propanoate 
• 253152-06-6 5-(1''-Ethoxyethoxy)-1-[1'-(phenylsulfanyl)cyclohexyl]pentanol 
• 253152-07-7 6-(1''-Ethoxyethoxy)-1-[1'-(phenylsulfanyl)cyclohexyl]hexanol 
• 253152-09-9 9-(1''-Ethoxyethoxy)-1-[1'-(phenylsulfanyl)cyclohexyl]nonanol 
• 253152-10-2 12-(1''-Ethoxyethoxy)-1-[1'-(phenylsulfanyl)cyclohexyl]dodecan-1-ol 
• 331765-84-5 methyl-3-[(1'-phenylsulfanyl)cyclohexyl]-prop-2-enoate 
• 1026603-30-4 (E)-3-(1-Phenylsulfanyl-cyclohexyl)-acrylic acid ethyl ester 
• 127940-85-6 (2R,3R)-3-Hydroxy-2-methyl-3-(1-phenylsulfanyl-cyclohexyl)-thiopropionic acid S-phenyl ester 

Relevant articles and documents

Do the electronic effects of sulfur indeed control the π-selectivity of γ-sulfenyl enones? An investigation

The electronic effects of sulfur in γ-sulfenyl enones are not transmitted to the carbonyl carbon through the π bond as reported previously. The diastereoselectivity is rather controlled by a combination of several other factors. The steric effects arising

Transformation of Cyclic α-Phenylthio Aldehydes by Stereoselective Aldol Reactions and Phenylthio Migration into Spirocyclic Lactones and Ethers, and E-Allylic Alcohols with 1,4-Related Chiral Centres

syn- and anti-Selective aldol reactions between enolates of propionate esters and three α-phenylthio cycloalkanecarbaldehydes give single diastereoisomers of phenylthio alcohols which rearrange in acid with 5-hydroxy or 5-CO2H participation to give spiroc

A novel synthesis of α-(phenylthio)aldehydes

Addition of methoxy(phenylthio)methyllithium to ketones, followed by rearrangement of the adducts, provides a new method for the preparation of α-(phenylthio)aldehydes.The rearrangement is stereospecific.