33189-72-9

Basic information

• Product Name: TRANS-11-TETRADECENYL ACETATE
• Synonyms: (11E)-11-Tetradecenyl acetate;11E-14Ac;(11E)-Tetradecen-1-yl Acetate;(e)-11-tetradecenyl;11-Tetradecen-1-ol, acetate, (E)-;acetate,(e)-11-tetradecen-1-o;trans-11-Tetradecen-1-yl acetate;trans-11-tetradecenyl
• CAS NO: 33189-72-9
• Molecular Formula: C₁₆H₃₀O₂
• Molecular Weight: 254.41
• EINECS: 251-401-4
• Mol File: 33189-72-9.mol
• Article Data: 27

Chemical Properties

• Melting Point: <25℃
• Boiling Point: 316.2±11.0℃ (760 torr)
• Flash Point: 62 °C
• Appearance: /
• Density: 0.878±0.06 g/cm3 (20 ºC 760 Torr)
• Vapor Pressure: 0.000416mmHg at 25°C
• Refractive Index: 1.4481 (589.3 nm 20℃)
• Storage Temp.: −20°C
• Solubility: Chloroform (Slightly), DMSO (Slightly)
• Stability: Light Sensitive
• CAS DataBase Reference: TRANS-11-TETRADECENYL ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS-11-TETRADECENYL ACETATE(33189-72-9)
• EPA Substance Registry System: TRANS-11-TETRADECENYL ACETATE(33189-72-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 33189-72-9(Hazardous Substances Data)

Usage

Uses

(11E)-Tetradecen-1-yl Acetate is found in the sex pheromones of moths.

InChI:InChI=1/C16H30O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-18-16(2)17/h4-5H,3,6-15H2,1-2H3/b5-4+

Upstream product

• 35153-18-5 (E)-11-tetradecen-1-ol 
• 108-24-7 acetic anhydride 
• 60171-36-0 (Z)-Oct-2-ene-1,8-diol 
• 119265-30-4 1,8-diacetoxy-2Z-octene 
• 53463-68-6 1-bromo-10-decanol 
• 89236-99-7 1-tert-butoxy-tetradec-11-yne 
• 57586-92-2 14-tetrahydropyranyloxy-2(E)-tetradecene 
• 4101-68-2 1,10-dibromodecane 
• 19101-00-9 (11?hydroxyundecyl)triphenylphosphonium bromide 
• 123-38-6 propionaldehyde 
• 31502-26-8 (E)-1-bromo-hept-4-ene 
• 24469-79-2 (E)-hept-4-en-1-ol 
• 54340-70-4 ethyl (E)-4-heptenoic acid ester 
• 127-09-3 sodium acetate 

Downstream Products

• 20711-10-8 (Z)-11-tetradecenyl acetate 
• 35746-21-5 E,Z-11-tetradecen-1-al 
• 35153-18-5 (E)-11-tetradecen-1-ol 

Relevant articles and documents

Stereoselective synthesis of 11(E)-tetradecen-1-yl acetate-Sex pheromone of sod webworm (Loxostege sticticalis)

On the basic of Claisen rearrangement using orthoesters we carried out stereoselective synthesis of 11(E)-tetradecen-1-yl acetate, a sex pheromone of sod webworm (Loxostege sticticalis), which is a specially dangerous pests of crops.

SYNTHESIS OF PHEROMONES AND RELATED MATERIALS VIA OLEFIN METATHESIS

Methods for preparation of olefins, including 8- and 11-unsaturated monoenes and polyenes, via transition metathesis-based synthetic routes are described. Metathesis reactions in the methods are catalyzed by transition metal catalysts including tungsten-, molybdenum-, and ruthenium-based catalysts. The olefins include insect pheromones useful in a number of agricultural applications.

Production of pheromones and fragrances from substituted and unsubstituted 1-alken-3yl alkylates

Compounds of the formula (I) wherein R2 is a branched or unbranched, saturated or ethylenically mono or di unsaturated aliphatic radical, Z is —CH2OH, —CH2OAc or —CHO, m is a whole positive integer of one or more, and Ac is an acetyl group are synthesized by a process wherein a 1-alken-3-yl alkylate, is reacted with a halo alkanol Grignard reagent.