332061-63-9

Upstream product

• 279684-94-5 Benzoic acid (R)-1-((2R,3S)-3-methyl-oxiranyl)-3-trimethylsilanyl-prop-2-ynyl ester 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 279684-69-4 (2R,3R,4R)-hex-5-yn-2,3,4-triol 2-benzoate ester 
• 279684-66-1 (3S,4R,5S)-1-(trimethylsilyl)-4,5-epoxyhex-1-yn-3-ol 
• 279684-67-2 (3R,4R,5S)-4,5-epoxyhex-1-yn-3-ol 
• 53723-96-9 (2E)-6-(trimethylsilyl)hex-2-en-5-yn-4-one 

Downstream Products

• 279684-73-0 (2R,3R,4R)-3,4-bis(tert-butyldiphenylsiloxy)-hex-5-yn-2-ol 
• 279684-75-2 (2S,3R,4R)-3,4-bis(tert-butyldiphenylsiloxy)-hex-5-yn-2-ol 
• 279684-78-5 3,4-bis-(tert-butyldiphenylsilyl)-1,5-anhydro-2,6-dideoxy-L-xylo-hex-1-enitol 
• 174810-85-6 3,4-bis(tert-butyldiphenylsilyl)-1,5-anhydro-2,6-dideoxy-D-arabino-hex-1-enitol 

Relevant academic research and scientific papers

Discovery of the tungsten carbonyl-catalyzed endo-selective alkynyl alcohol cycloisomerization reaction: Applications to stereoselective syntheses of D-olivose, D-olivose disaccharide substructures of landomycin and mithramycin

An account of the discovery of the tungsten carbonyl-catalyzed endo-selective cycloisomerization of alkynyl alcohols to dihydropyrans is described. The utility of this new chemical transformation involving tungsten vinylidene catalytic intermediates is de

Stereoselective glycosylations of a family of 6-deoxy-1,2-glycals generated by catalytic alkynol cycloisomerization

Photolysis of 0.25 equiv of W(CO)6 in the presence of tertiary amines (triethylamine or DABCO) and highly functionalized terminal alkynyl alcohols catalyzes single-step, high-yield cycloisomerization to endocyclic enol ethers. This transformati