174810-85-6

Upstream product

• 78086-61-0 (2R,3S,4R)-2-Methyl-3,4-dihydro-2H-pyran-3,4-diol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 279684-73-0 (2R,3R,4R)-3,4-bis(tert-butyldiphenylsiloxy)-hex-5-yn-2-ol 
• 332061-63-9 Benzoic acid (1R,2R,3R)-2,3-bis-(tert-butyl-diphenyl-silanyloxy)-1-methyl-pent-4-ynyl ester 
• 279684-94-5 Benzoic acid (R)-1-((2R,3S)-3-methyl-oxiranyl)-3-trimethylsilanyl-prop-2-ynyl ester 
• 279684-69-4 (2R,3R,4R)-hex-5-yn-2,3,4-triol 2-benzoate ester 
• 279684-66-1 (3S,4R,5S)-1-(trimethylsilyl)-4,5-epoxyhex-1-yn-3-ol 
• 279684-67-2 (3R,4R,5S)-4,5-epoxyhex-1-yn-3-ol 
• 53723-96-9 (2E)-6-(trimethylsilyl)hex-2-en-5-yn-4-one 

Relevant academic research and scientific papers

On the stereochemistry of aryl C-glycosides: Unusual behavior of bis-TBDPS protected aryl C-olivosides

A D-olivosyl donor in which the C(3) and C(4) hydroxyls are both protected by an extremely bulky group, t-BuPh2Si, undergoes aryl C-glycosidation in an α-selective manner, and the product configuration remains unchanged under various Lewis acid

Stereoselective glycosylations of a family of 6-deoxy-1,2-glycals generated by catalytic alkynol cycloisomerization

Photolysis of 0.25 equiv of W(CO)6 in the presence of tertiary amines (triethylamine or DABCO) and highly functionalized terminal alkynyl alcohols catalyzes single-step, high-yield cycloisomerization to endocyclic enol ethers. This transformati