333380-82-8Relevant academic research and scientific papers
Synthesis of enantiopure benzyl homoallylamines by indium-mediated barbier-type allylation combined with enzymatic kinetic resolution: Towards the chemoenzymatic synthesis of N-containing heterocycles
Hietanen, Ari,Saloranta, Tuna,Rosenberg, Sara,Laitinen, Evelina,Leino, Reko,Kanerva, Liisa T.
scheme or table, p. 909 - 919 (2010/04/23)
Barbier-type indium-mediated allylations of different N, N(dimethylsulfamoyl)-protected aldimines with a number of allyl bromides followed by high-yielding deprotection afforded allylic amines in good to excellent yields, The racemic amines were then subj
Room-temperature highly diastereoselective Zn-mediated allylation of chiral N-tert-butanesulfinyl imines: Remarkable reaction condition controlled stereoselectivity reversal
Sun, Xing-Wen,Xu, Ming-Hua,Lin, Guo-Qiang
, p. 4979 - 4982 (2007/10/03)
(Chemical Equation Presented) An efficient method for the highly diastereoselective synthesis of chiral homoallylic amines by Zn-mediated allylation of chiral N-tert-butanesulfinyl imines at room temperature was developed. By simply tuning the reaction co
Aluminum-controlled reactivity and diastereoselectivity toward radical reactions of optically active aldimines with metallic samarium
Yanada,Okaniwa,Kaieda,Ibuka,Takemoto
, p. 1283 - 1286 (2007/10/03)
The intermolecular pinacol-type coupling reaction and allylation reaction of optically active imines bearing a β-hydroxy group were performed stereoselectively with metallic samarium after treatment of the imines with trimethylaluminum.
