3335-68-0

Usage

InChI:InChI=1/C13H16N4O4/c18-16(19)11-6-7-12(13(8-11)17(20)21)15-14-9-10-4-2-1-3-5-10/h6-10,15H,1-5H2

Upstream product

• 13830-44-9 7-'exo'-Hydroxy-bicyclo<4.1.0>heptan 
• 119-26-6 (2,4-dinitro-phenyl)-hydrazine 
• 2043-61-0 cyclohexanecarbaldehyde 
• 3218-02-8 cyclohexylmethylamine 
• 10330-36-6 exo-7-acetylbicyclo<4.1.0>heptane 
• 34780-92-2 7c-acetoxy-(1r)-norcarane 
• 100-50-5 3-Cyclohexene-1-carboxaldehyde 
• 530113-81-6 C₁₉H₄₂O₂Si₂ 
• 98-89-5 Cyclohexanecarboxylic acid 
• 100-49-2 cyclohexylmethyl alcohol 

Relevant academic research and scientific papers

Selective reduction of carboxylic acids to aldehydes catalyzed by B(C 6F5)3

B(C6F5)3 efficiently catalyzes hydrosilylation of aliphatic and aromatic carboxylic acids to produce disilyl acetals under mild conditions. Catalyst loadings can be as low as 0.05 mol %, and bulky tertiary silanes are favored to give selectively the acetals. Acidic workup of the disilyl acetals results in the formation of aldehydes in good to excellent yields.

Copper(I)/ABNO-catalyzed aerobic alcohol oxidation: Alleviating steric and electronic constraints of Cu/TEMPO catalyst systems

Cu/TEMPO catalyst systems promote efficient aerobic oxidation of sterically unhindered primary alcohols and electronically activated substrates, but they show reduced reactivity with aliphatic and secondary alcohols. Here, we report a catalyst system, consisting of (MeObpy)CuI(OTf) and ABNO (MeObpy =4,4′-dimethoxy-2,2′-bipyridine; ABNO = 9-azabicyclo[3.3.1]nonane N-oxyl), that mediates aerobic oxidation of all classes of alcohols, including primary and secondary allylic, benzylic, and aliphatic alcohols with nearly equal efficiency. The catalyst exhibits broad functional group compatibility, and most reactions are complete within 1 h at room temperature using ambient air as the source of oxidant.

Oxidation of unactivated primary aliphatic amines catalyzed by an electrogenerated 3,4-azaquinone species: A small-molecule mimic of amine oxidases

High catalytic performance of the electrogenerated amine oxidase mimic 3,4-iminoquinone 1ox is observed under metal-free conditions in the chemoselective oxidation reaction of unactivated primary aliphatic amines.