333717-22-9

Upstream product

• 164665-83-2 2,3-O-isopropylidene-1-O-p-methoxybenzyl-α-D-mannofuranoside 
• 14131-84-1 2,3:5,6-di-O-isopropylidene-α-D-mannofuranose 
• 824-94-2 p-methoxybenzyl chloride 
• 7757-38-2 2,3:5,6-di-O-isopropylidene-α-D-mannofuranose 

Downstream Products

• 333717-23-0 (R)-1-[(3aS,4R,6S,6aS)-6-(4-Methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-but-3-en-1-ol 
• 333717-27-4 4-methoxybenzyl 6,7,8,-trideoxy-2,3-O-(1-methylethylidene)-α-D-manno-oct-7-enofuraniside 
• 1382059-94-0 4-methoxybenzyl 5-deoxy-2,3-O-isopropylidene-5-(1H-tetrazol-5-yl)-α-D-lyxofuranoside 
• 1382059-93-9 4-methoxybenzyl 5-cyano-5-deoxy-2,3-O-isopropylidene-α-D-lyxofuranoside 
• 1382059-92-8 4-methoxybenzyl 2,3-O-isopropylidene-α-D-lyxofuranoside 
• 1382060-21-0 (5S,6S,7R)-7-O-formyl-5,6-O-isopropylidene-5,6,7,8-tetrahydrotetrazolo[1,5-a]pyridine-5,6,7-triol 
• 1382060-04-9 (4R)-4-methoxybenzyl 2,3-O-isopropylidene-4C-(1H-tetrazol-5-yl)-β-L-erythrofuranoside 
• 1382060-03-8 4-methoxybenzyl 2,3-O-isopropylidene-α-D-lyxofuranosidurononitrile 
• 333717-25-2 (R)-4-Benzyloxy-5-{(4R,5S)-5-[methoxy-(4-methoxy-benzyloxy)-methyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-5-oxo-pentanal 
• 333717-21-8 p-methoxybenzyl 6,7,8-trideoxy-5-O-benzyl-2,3-O-(1-methylethylidene)-α-D-manno-oct-7-enofuranoside 
• 154815-12-0 (3aR,9R,9aR,9bS)-octahydro-2,2-dimethyl-9-(phenylmethoxy)-1,3-dioxolo[4,5-a]indolizine 
• 85624-09-5 (3aR,9R,9aR,9bS)-octahydro-2,2-dimethyl-[1,3]dioxolo[4,5-a]indolizin-9-ol 
• 72741-87-8 swainsonine 

Relevant academic research and scientific papers

Alternate synthesis to D-glycero-β-D-manno-heptose 1,7-biphosphate

D-glycero-β-D-manno-heptose 1,7-biphosphate (HBP) is an enzymatic intermediate in the biosynthesis of the heptose component of lipopolysaccharide (LPS), and was recently revealed to be a pathogen-associated molecular pattern (PAMP) that allows detection o

PHOSPHORYLATED HEPTOSE COMPOUNDS : PROCESS FOR THEIR PREPARATION AND USE

Processes for the preparation of phosphorylated heptose compounds are provided. Embodiments of the invention relate to the chemical synthesis of heptopyranose phosphate compounds. Also, embodiments of the invention relate to the use of compounds according

Synthesis of tetrazole-fused glycosides by a tandem fragmentation- cyclization reaction

The fragmentation of anomeric alkoxyl radicals (ARF) and the subsequent intramolecular cyclization promoted by hypervalent iodine reagents provide an excellent method for the synthesis of tetrazolo-sugars. This new reaction offers additional advantages for the synthesis of these compounds, including the ready availability of the starting materials, experimental simplicity, mild conditions, and good yields.

Allylated monosaccharides as precursors in triple reductive amination strategies: Synthesis of castanospermine and swainsonine

The feasibility of the triple-reductive amination reaction for the synthesis of complex indolizidine frameworks is illustrated by application to the potent glycosidase inhibitors castanospermine and swainsonine. The target compounds were obtained from known carbohydrate precursors in yields of 23 and 14%, over nine and 13 steps, respectively. The iodoetherification reaction of allylated monosaccharides was shown to be a practical reaction for the synthesis of the tricarbonyl precursors for the key triple reductive amination reactions.