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(2S,3R,4R)-3-benzyloxy-2-iodomethyltetrahydrofuran-4-ol is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

334784-71-3

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334784-71-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 334784-71-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,3,4,7,8 and 4 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 334784-71:
(8*3)+(7*3)+(6*4)+(5*7)+(4*8)+(3*4)+(2*7)+(1*1)=163
163 % 10 = 3
So 334784-71-3 is a valid CAS Registry Number.

334784-71-3Relevant articles and documents

Synthesis of substituted tetrahydrofuran by electrophile-induced cyclization of 4-pentene-1,2,3-triols - An example of 5-exo versus 5-endo cyclization governed by the electrophile

Bravo, Fernando,Castillon, Sergio

, p. 507 - 516 (2001)

Differently protected 4-pentene-1,2,3-triols 5-8 were obtained from glyceraldehyde and submitted to iodine-based electrophile-induced cyclization to give tetrahydrofuran derivatives 10 and 18, with high chemo-, regio-, and stereo-selectivity, through a 5-exo cyclization process. However, when an electrophilic selenium reagent was treated with similar alkene triols 5, 7, and 8, the product depended on the protecting group at the primary hydroxy moiety. Thus, while compounds 5a and 5b, unprotected at the primary hydroxy group, give compounds 26 and 27, and 32 and 33, respectively, through a 5-exo cyclization process, compounds 7 and 8, protected at the primary hydroxy group, give the 5-endo cyclization products 22-25 and 28-31 in good yields. The electrophile-induced cyclization of 4-pentene-1,2,3-triols to give tetrahydrofuran derivatives can be directed towards a 5-exo process by the use of iodine or, when the primary hydroxy group is unprotected, selenium. When the primary hydroxy group is protected, use of selenium results in 5-endo cyclization.

Synthesis of tetrahydrofurans through a novel pseudo-meso-trick

Babjak, Matej,Remeň, L'ubo?,Karlubíková, Ol'ga,Gracza, Tibor

, p. 1609 - 1611 (2007/10/03)

Diastereoselective synthesis of trisubstituted tetrahydrofuran (D-lyxo-4) from the equimolar diastereomeric mixture of D-erythro-/D-threo-1-pentenitols (1) is described. The synthesis exploits a sequence of two novel reactions: diastereospecific palladium

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