373646-99-2Relevant academic research and scientific papers
Stereoselective synthesis of both enantiomers of 1,4-anhydro-alditols, 1,4-anhydro-2-amino-alditols and D- and L-isonucleosides from 2,3-O-isopropylidene-D-glyceraldehyde using iodine-induced cyclization as the key step
Bravo, Fernando,Diaz, Yolanda,Castillon, Sergio
, p. 1635 - 1643 (2007/10/03)
We have stereoselectively prepared the enantiomeric 1,4-anhydro-alditols (-)-15 and (+)-15, 1,4-anhydro-2-amino-aldi-tols (-)-19 and (+)-19, and isonucleosides (-)-22, (+)-22 and 25, from 2,3-O-isopropylidene-D-glyceraldehyde. The key step was the iodine-
