334834-23-0

Upstream product

• 134198-40-6 6-O-benzoyl-3-O-benzyl-1,2-O-isopropylidene-5-O-methanesulfonyl-α-D-glucofuranose 
• 334834-37-6 1,6-anhydro-2,3,4-triO-trimethylsilyl-β-L-idopyranose 
• 42926-91-0 3-O-benzyl-1,6-anhydro-β-L-idopyranose 
• 60619-47-8 1,6-anhydro-β-L-idopyranose 
• 87357-54-8 6-deoxy-1,2:3,5-di-O-isopropylidene-α-D-xylo-hex-5-enofuranose 
• 81562-09-6 6-hydroxy-1,2:3,5-di-O-isopropylidene-α-D-glucofuranoside 
• 98-88-4 benzoyl chloride 

Downstream Products

• 334834-29-6 2-O-{6-O-acetyl-2,4-di-O-benzyl-3-O-[(p-nitrophenyl)formyl]-α-D-mannopyranosyl}-4-O-benzoyl-3-O-benzyl-1,6-anhydro-β-L-gulopyranose 
• 334834-24-1 4-O-benzoyl-3-O-benzyl-1,6-anhydro-β-L-gulopyranose 

Relevant academic research and scientific papers

Biologically potent L-hexoses and 6-deoxy-L-hexoses: Their syntheses and applications

This account describes our recent work in the development of new methodologies to prepare rare and biologically potent L-hexoses and 6-deoxy-L-hexoses, from cheapest D-glucose, via L-hexofuranoses and 1,6-anhydro-β-L-hexopyranoses as key building blocks. Their applications in the syntheses of heparin oligosaccharides, the carbohydrate moiety of bleomycin A2, and L-acovenose are also summarized here.