335-12-6Relevant articles and documents
Thermal decomposition of branched-chain perfluoroalkanes
Tortelli, V.,Tonelli, C.,Corvaja, C.
, p. 165 - 174 (1993)
The pyrolysis of some branched perfluoroalkanes has been studied.Homolytic cleavage of the most hindered carbon-carbon bond occurs, followed by coupling and rearrangement of the radicals so formed.This mechanism accounts for all the reaction products.Some kinetic and thermodynamic data are presented.