Journal of Fluorine Chemistry p. 165 - 174 (1993)
Update date:2022-08-02
Topics:
Tortelli, V.
Tonelli, C.
Corvaja, C.
The pyrolysis of some branched perfluoroalkanes has been studied.Homolytic cleavage of the most hindered carbon-carbon bond occurs, followed by coupling and rearrangement of the radicals so formed.This mechanism accounts for all the reaction products.Some kinetic and thermodynamic data are presented.
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