335004-12-1

Basic information

• Product Name: Carbamic acid, [[2,4,6-tris(1-methylethyl)phenyl]sulfonyl]-, 1,1-dimethylethyl ester
• CAS NO: 335004-12-1
• Molecular Formula: C20H33NO4S
• Molecular Weight: 383.552
• Mol File: 335004-12-1.mol

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [[2,4,6-tris(1-methylethyl)phenyl]sulfonyl]-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [[2,4,6-tris(1-methylethyl)phenyl]sulfonyl]-, 1,1-dimethylethyl ester(335004-12-1)
• EPA Substance Registry System: Carbamic acid, [[2,4,6-tris(1-methylethyl)phenyl]sulfonyl]-, 1,1-dimethylethyl ester(335004-12-1)

Safety Data

• Hazardous Substances Data: 335004-12-1(Hazardous Substances Data)

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 105536-22-9 2,4,6-triisopropylbenzene sulfonamide 

Downstream Products

• 335004-20-1 (E)-N,N'-bis(tert-butyloxycarbonyl)-N,N'-bis[(2,4,6-triisopropylphenyl)sulfonyl]-2-butene-1,4-diamine 
• 357675-47-9 C₄₄H₇₀N₂O₈S₂ 
• 615269-52-8 N-(2-bromomethylbenzyl)-N-(tert-butyloxycarbonyl)-(2,4,6-triisopropyl)benzenesulfonamide 
• 674769-26-7 N-[(E)-4-bromo-2-butenyl]-N-(tert-butyloxycarbonyl)-(2,4,6-triisopropylphenyl)sulfonamide 
• 918401-82-8 N-[(E)-4-chloro-2-buten-1-yl]-N-(tert-butoxycarbonyl)-(2,4,6-triisopropyl)phenylsulfonamide 
• 918401-84-0 (E,E)-1,11-bis[(2,4,6-triisopropylphenyl)sulfonyl]-6-[(4-iodophenyl)sulfonyl]-1,6,11-triazaundeca-3,8-diene 
• 918401-85-1 (E,E,E)-1,6-bis[2,4,6-(triisopropyl)phenylsulfonyl]-11-(4-iodophenylsulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-triene 
• 918401-83-9 (E,E)-1,11-bis(tert-butoxycarbonyl)-1,11-bis[(2,4,6-triisopropylphenyl)sulfonyl]-6-[(4-iodophenyl)sulfonyl]-1,6,11-triazaundeca-3,8-diene 
• 615269-57-3 1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-3,4;8,9-dibenzo-1,6,11-triazaundecane 
• 615269-62-0 11-[(4-methylphenyl)sulfonyl]-1,6-bis[(2,4,6-triisopropylphenyl)sulfonyl]-3,4;8,9;13,14-tribenzo-1,6,11-triazacyclopentadecane 
• 615269-56-2 1,11-bis(tert-butyloxycarbonyl)-6-[(4-methylphenyl)sulfonyl]-1,11-bis[(2,4,6-triisopropylphenyl)sulfonyl]-3,4;8,9-dibenzo-1,6,11-triazaundecane 
• 615269-54-0 1,11-bis(tert-butyloxycarbonyl)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-3,4;8,9-dibenzo-1,6,11-triazaundecane 
• 219839-36-8 (Z)-1,4-bis[(2,4,6-triisopropylphenyl)sulfonyl]-1,4-diamine-2-butene 
• 357675-48-0 (E,E,Z)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6,11-triazacyclopentadeca-3,8,13-triene 

Relevant articles and documents

Metal complexes of 15-membered triolefinic macrocycles. (E,E,Z)-1,6,11-Tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene and its palladium(0), platinum(0), and silver(I) complexes

The preparation of the 15-membered macrocycle (E,E,Z)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene is reported. This cyclic triolefin forms stable complexes with palladium(0) and platinum(0), and a moderately stable complex with silver(I) tetrafluoroborate.

Preparation of a novel homogeneous bimetallic Rhodium/Palladium ionic catalyst and its application for the catalytic hydrogenation of nitrile butadiene rubber

A new hybrid second-generation poly (propylene imine) dendrimer terminated by nitrogen-containing triolefinic macrocycle on the periphery (G2-M) was synthesized. The bimetallic Rhodium (III)/Palladium (II) (Rh3+/Pd2+) dendrimer-stabilized catalysts (G2-M(Rh3+xPd2+10-x)) were prepared by a co-complexation route within G2-M and analyzed by1H NMR, XRD and XPS. The catalytic activity, selectivity and separation capability for the hydrogenation of nitrile-butadiene rubber (NBR) catalyzed by the G2-M(Rh3+xPd2+10?x) have been researched. As a novel catalyst system, the bimetallic ions of Rh3+and Pd2+have influenced on the catalytic activity for the hydrogenation of NBR, which can be related to electron-deficiency effect of Rh3+resulting from the interaction of Rh3+and Pd2+within G2-M.

Preparation of nitrogen-containing 15-membered triolefinic macrocycles: (E,E,E)-1,6,11-tris(arylsulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-trienes

Three routes to (E,E,E)-1,6,11-tris(arylsulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-trienes are described. Optimization of the preparation of key intermediates has opened the way to efficient synthesis of a broad variety of 15-membered, nitrogen-containing triolefinic macrocycles.