335004-12-1Relevant articles and documents
Metal complexes of 15-membered triolefinic macrocycles. (E,E,Z)-1,6,11-Tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene and its palladium(0), platinum(0), and silver(I) complexes
Cortès, Jordi,Moreno-Maas, Marcial,Pleixats, Roser
, p. 4337 - 4339 (2001)
The preparation of the 15-membered macrocycle (E,E,Z)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene is reported. This cyclic triolefin forms stable complexes with palladium(0) and platinum(0), and a moderately stable complex with silver(I) tetrafluoroborate.
Preparation of nitrogen-containing 15-membered triolefinic macrocycles: (E,E,E)-1,6,11-tris(arylsulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-trienes
Cerezo, Silvia,Cortès, Jordi,Galvan, David,Lago, Elena,Marchi, Caroline,Molins, Elies,Moreno-Ma?as, Marcial,Pleixats, Roser,Torrejón, Javier,Vallribera, Adelina
, p. 329 - 337 (2007/10/03)
Three routes to (E,E,E)-1,6,11-tris(arylsulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-trienes are described. Optimization of the preparation of key intermediates has opened the way to efficient synthesis of a broad variety of 15-membered, nitrogen-containing triolefinic macrocycles.