335004-16-5Relevant academic research and scientific papers
15-Membered triolefinic macrocycles as stabilizers of palladium(0) nanoparticles
Serra-Muns, Anna,Soler, Roger,Badetti, Elena,De Mendoza, Paula,Moreno-Manas, Marcial,Pleixats, Roser,Sebastian, Rosa M.,Vallribera, Adelina
, p. 1584 - 1594 (2007/10/03)
15-Membered triolefinic macrocycles form complexes with palladium(0). However, metal nanoparticles are formed instead of discrete complexes if substituents provided with the ability to stabilize nanoparticles are incorporated into the structure of the mac
Preparation of nitrogen-containing 15-membered triolefinic macrocycles: (E,E,E)-1,6,11-tris(arylsulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-trienes
Cerezo, Silvia,Cortès, Jordi,Galvan, David,Lago, Elena,Marchi, Caroline,Molins, Elies,Moreno-Ma?as, Marcial,Pleixats, Roser,Torrejón, Javier,Vallribera, Adelina
, p. 329 - 337 (2007/10/03)
Three routes to (E,E,E)-1,6,11-tris(arylsulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-trienes are described. Optimization of the preparation of key intermediates has opened the way to efficient synthesis of a broad variety of 15-membered, nitrogen-containing triolefinic macrocycles.
