3351-47-1

Upstream product

• 106-43-4 para-chlorotoluene 

Downstream Products

• 85649-54-3 Na⁽¹⁺⁾*Ge(CH₃C₆H₄)3^(1-)=NaGe(CH₃C₆H₄)3 
• 926312-90-5 tert-Bu₂MeSiGe(p-tolyl)3 
• 926312-91-6 tert-Bu₂MeSiGe(p-tolyl)2Cl 
• 926312-92-7 (tert-Bu)2MeSiGe(p-tolyl)2-Ge(p-tolyl)2SiMe(tert-Bu)2 
• 909779-64-2 [tris(p-tolyl)germyl]lithium 
• 153245-98-8 {Os(Ge(C₆H₄CH₃)3)H(CO)2(P(C₆H₅)3)2}*CH₂Cl₂ 
• 153245-96-6 {Ru(Ge(C₆H₄CH₃)3)H(CO)2(P(C₆H₅)3)2}*CH₂Cl₂ 

Relevant academic research and scientific papers

Heavy cyclopropene analogues R4SiGe2 and R4Ge3 (R = SiMetBu2) - New members of the cyclic digermenes family

1H-Siladigermirene R4SiGe2 (2a) and 1H-trigermirene R4Ge3 (2b) (R = SiMetBu2) with a Ge{double bond, long}Ge double bond were synthesized by the reaction of tetrachlorodigermane RGeCl2-GeCl2R with dilithiosilane R2SiLi2 and dilithiogermane R2GeLi2, respectively. The skeletal Ge{double bond, long}Ge double bond of 2a is trans-bent (51.0(2)°) with a bond distance of 2.2429(6) A?. The reaction of both 2a and 2b with CH2Cl2 resulted in the formation of unusual four-membered ring compounds 5a and 5b as a result of a ring expansion reaction. 1H-Trisilirene 7a and 3H-disilagermirene 7b with an Si{double bond, long}Si double bond also smoothly reacted with CH2Cl2 to yield the four-membered ring systems 8a and 8b, respectively.

The acidities of some aryl-substituted germanes in liquid ammonia

Proton magnetic resonance techniques have been used to determine the acidities of some aryl-substituted germanes in liquid ammonia. It was found that increasing aryl substitution caused a reduction in acidity. Factors such as solvation, ion pairing, and structural effects are used to explain the order of acidities.