335171-91-0Relevant academic research and scientific papers
The asymmetric catalytic aldol reaction of allenolates with aldehydes using N-fluoroacyl oxazaborolidine as the catalyst
Li, Guigen,Wei, Han-Xun,Phelps, Brian S.,Purkiss, David W.,Kim, Sun Hee
, p. 823 - 826 (2001)
matrix presented The asymmetric catalytic aldol reaction of silyl allenolates with aldehydes has been achieved by using N-C3F7CO oxazaborolidine as the catalyst. The fluoroacyl group of the catalyst was found to be crucial for control of enantioselectivity. The reaction provides the first enantioselective approach to β-halo Baylis-Hillman-type adducts.
