335248-23-2Relevant academic research and scientific papers
Evaluation of zirconium and hafnium complexes that contain the electron-withdrawing diamido/donor ligand [(2,6-Cl2C 6H3NCH2CH2)2NCH 3]2- for the polymerization of 1-he
Schrock, Richard R.,Adamchuk, Jennifer,Ruhland, Klaus,Lopez, L. Pia H.
, p. 857 - 866 (2008/10/09)
The synthesis of zirconium and Hafnium complexes that contain the electron-withdrawing diamido/donor ligand for the polymerization of 1-Hexene was described. Isobutene was found to insert slowly into the M-R bond of the initiators in a 1,2 manner and was
CH bond activation in cations of the type {[(2,4,6-Me3 C6H2NCH2CH2)2NMe] ZrR}+ and a simple solution that yields a catalyst for the living polymerization of 1-hexene
Schrock, Richard R.,Bonitatebus Jr., Peter J.,Schrodi, Yann
, p. 1056 - 1058 (2008/10/08)
{[(MesNCH2CH2)2NMe]ZrMe} [B(C6F5)4] and intermediates in the polymerization reaction of 1-hexene that are formed from it decompose as a consequence of CH activation in an ortho methyl group
