33559-14-7Relevant academic research and scientific papers
Oxidation of Triorganosilanes and Related Compounds by Chlorine Dioxide
Grabovskiy,Kabal’nova
, p. 2391 - 2402 (2022/01/22)
Abstract: Oxidation of triethylsilane, tert-butyldimethylsilane, dimethylphenylsilane, triphenylsilane, 1,1,1,2tetramethyl-2-phenyldisilane, tris(trimethylsilyl)silane, hexamethyldisilane, tetrakis(trimethylsilyl)silane, 1,1,3,3tetraisopropyldisiloxane with chlorine dioxide was carried out. The reaction products of studied triorganosilanes with chlorine dioxide in an acetonitrile solution were the corresponding silanols and siloxanes. A mechanism explaining the formation of products and the observed regularities of the oxidation of silanes with chlorine dioxide has been proposed. A thermochemical analysis of some possible pathways in the gas phase using methods G4, G3, M05, and in an acetonitrile solution by the SMD-M05 method was carried out. The oxidation process can occur both with the participation of ionic and radical intermediates, depending on the structure of the oxidized substrate and medium.
L'electrosynthese, une voie simple d'acces aux di- et polysilanes
Biran, C.,Bordeau, M.,Pons, P.,Leger, M.-P.,Dunogues, J.
, p. C17 - C20 (2007/10/02)
Electrochemical reduction of chlorosilanes, at constant current intensity, in a single compartment cell fitted with a sacrificial aluminium anode, is a practical and convenient route to di-, tri-, and poly-silanes.
