335645-90-4Relevant academic research and scientific papers
Pentadienyl transfer reagents based on zirconium: Preparation and reactions with carbonyl compounds
Bertus, Philippe,Drouin, Ludovic,Laroche, Christophe,Szymoniak, Jan
, p. 1375 - 1383 (2007/10/03)
A variety of 2,4-pentadienylzirconiums were generated by reacting pentadienyl ethers with zirconocene 'Cp2Zr'. These complexes underwent a highly γ-regioselective and anti-stereoselective in situ addition with carbonyl compounds to afford bis(h
Pentadienylzirconium compounds: Easily accessible new reagents for selective pentadienylation reactions
Bertus, Philippe,Cherouvrier, Franck,Szymoniak, Jan
, p. 1677 - 1680 (2007/10/03)
2,4-Pentadienylzirconium complexes are generated from 2,4- or 2,2′-pentadienyl ethers in turn. These compounds react in situ with aldehydes and ketones in a totally γ-regioselective manner and with predominant anti stereoselectivity to produce bis(homoall
