33567-67-8

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 85526-09-6 Lithium; (methyl-phenyl-amino)-ethynethiolate 
• 7652-06-4 chloroethynyl-trimethyl-silane 
• 100-61-8 N-methylaniline 
• 708-88-3 N-methyl-N-(trichlorovinyl)aniline 

Downstream Products

• 72809-70-2 Methyl-(4-methyl-3-trimethylsilanyloxy-pent-3-en-1-ynyl)-phenyl-amine 
• 72809-85-9 4,4-Dimethyl-3-(methyl-phenyl-amino)-2-(2-methyl-1-trimethylsilanyloxy-propenyl)-cyclobut-2-enone 
• 65957-07-5 N-isopropyl-N’-methyl-N,N'-diphenylethene-1,1-diamine 
• 80608-30-6 4-(N-Methylanilino)-2-oxo-3-butinsaeure-cholesterylester 
• 67857-53-8 3--N¹,N²-diphenylpropiolamidin 
• 86930-73-6 2-Anilino-4--3-trimethylsilylchinolin 
• 139007-97-9 (E)-6-(N-Methylanilino)hex-3-en-5-in-2-on 
• 72809-93-9 N-Methyl-3-oxo-4,4,N-triphenyl-butyramide 
• 72809-82-6 2-(2,2-Diphenyl-1-trimethylsilanyloxy-vinyl)-3-(methyl-phenyl-amino)-4,4-diphenyl-cyclobut-2-enone 
• 72809-89-3 2-Diphenylacetyl-3-(methyl-phenyl-amino)-4,4-diphenyl-cyclobut-2-enone 
• 72809-73-5 4,4-Diphenyl-3-trimethylsilanyloxy-but-3-enoic acid methyl-phenyl-amide 
• 72809-97-3 4-(N-methylanilino)-1,1-diphenyl-3-butyne-2-on 
• 65957-22-4 N¹-methyl-N¹,N²-diphenylacetamidine 
• 168106-72-7 (E)-5-(N-Methylanilino)pent-2-en-4-inal 

Relevant academic research and scientific papers

Synthesis of 'push-pull' enynes

'Push-pull' enynes 1a-1f are easily available by Pd catalyzed coupling of stannyl-ynamines 15 and silylynamines 16 with β-iodo-enones 8 (Schemes 7 and 8).

Synthese von 5-(Dialkylamino)-5-X-pentadienalen aus 'Push-Pull'-Eninen (1>

5-Aminopent-2-ene-4-inals 1 are easily available by Pd(0)-catalyzed coupling of stannyl ynamines 6 or silyl ynamines 7 with 3-iodoacroleine.They react nearly quantitatively with acids like HCl or AcOH to give 5-amino-5-X-pentadienals 2, which are of inter

A Novel Synthesis and Reactions of Aminoethynyl Sulfides

Reaction of the alkynide 2 with sulfur provides ready access to aminoethynyl sulfides 5 with different second substituents on the sulfide sulfur atom.Hydrolysis and cycloadditions with diphenylketene, phenyl isocyanate, or tosyl isothiocyanate prove the S-alkyl derivatives 5a, b to be typical ynamines, whereas amine addition to the silylthio compound 5c takes a different course.