33625-96-6Relevant academic research and scientific papers
Study of Methylidyne Radical (CH and CD) Reaction with 2,5-Dimethylfuran Using Multiplexed Synchrotron Photoionization Mass Spectrometry
Carrasco, Erica,Meloni, Giovanni
, p. 6118 - 6133 (2018/07/09)
At 298 K the reactions of 2,5-dimethlyfuran + CH(X2Θ) and + CD radicals were investigated using synchrotron radiation coupled with multiplexed photoionization mass spectrometry at the Lawrence Berkeley National Laboratory. Reaction products wer
METAL COMPLEXES WITH ALLYLANILINES. IV. SYNTHESIS AND REACTIVITY OF RHODIUM(I) COMPLEXES WITH 2-ALLYLANILINE AND N-ALLYLANILINE
Aresta, M.,Fazio, M. De
, p. 109 - 120 (2007/10/02)
The reaction of 2-allylaniline (2aa) with 2 (I) in toluene or benzene at room temperature affords the dimer 2 (II) in which the ligand acts as bidentate, being coordinated to the metal through the N atom and the olefinic group.II in CH2Cl2, isomerizes 2aa to trans-2-propenylaniline.This reaction goes also catalytically.Heating of II in benzene affords 2-methyl-indoline.N-Allylaniline (naa) reacts with I to give the deep violet diamagnetic complex Rh2Cl2(naa)3 (III), which is converted slowly into 2.When III is heated with an excess of naa, the ligand is catalytically transformed into propene, azobenzene, N-n-propylaniline, N-i-propylaniline, N-allylideneaniline and aniline, as the more abundant products.Moreover, III reacts with diphenylacetylene to afford 2,5-dihydro-1,2,3-triphenyl-4-methyl-pyrrole.The reaction of III with methylacetylene follows a more complex path, and products of dimerization and trimerization of the alkyne have been isolated.Carbon dioxide influences the oligomerization reaction.
SOME CATALYTIC PROPERTIES OF Rh(diphos)(η-BPh4)
Albano, P.,Aresta, M.
, p. 243 - 246 (2007/10/02)
The covalent complex Rh(diphos)(η-BPh4) (I) reacts with CO in polar solvents to afford the cationic dicarbonyl cis-(BPh4).I is an effective catalyst for methylacetylene oligomerization and allene polymerization.In the presence of CO2 and methylacetylene, I affords 4,6-dimethyl-2-pyrone.
